EASY
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Which one is not correct for gaseous state obeying Van der Waal's equation?

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Important Questions on States of Matter

EASY
At very high pressures, the compressibility factor of one mole of a gas is given by:
MEDIUM
Given, van der Waal's constant for NH3, H2, O2 and CO2 are respectively 4.17, 0.244, 1.36 and 3.59. Which one of the following gases is most easily liquefied?
HARD
If Z is the compressibility factor, then Van der Waal's equation at low pressure can be written as:
HARD
For one mole of a van der Waals' gas, the compressibility factor Z=pVRT at a fixed volume will certainly decrease, if
[Given : " a " and " b " are standard parameters for van der Waals' gas]
 
EASY

Given below are two statement : one is labelled as Assertion A and the other is labelled as Reason R.
Assertion A:SO2( g) is adsorbed to a large extent than H2( g) on activated charcoal.

Reason R : SO2( g) has a higher critical temperature than H2( g)

In the light of the above statements, choose the most appropriate answer from the options given below.

EASY
At a given temperature T, gases Ne, Ar, Xe and Kr are found to deviate from ideal gas behaviour. Their equation of state is given as p=RTV-b at T. Here, b is the van der Waals constant. Which gas will exhibit steepest increase in the plot of Z (compression factor) vs p?
EASY

The number of statement's, which are correct with respect to the compression of carbon dioxide from point (a) in the Andrews isotherm from the following is _________.

Question Image

A. Carbon dioxide remains as a gas upto point (b)
B. Liquid carbon dioxide appears at point (c)
C. Liquid and gaseous carbon dioxide coexist between points (b) and (c)
D. As the volume decreases from (b) to (c), the amount of liquid decreases 

HARD

A gas has a compressibility factor of 0.5 and a molar volume of 0.4 dm3 mol-1 at a temperature of 800 K and pressure x atm. If it shows ideal gas behaviour at the same temperature and pressure, the molar volume will be  y dm3 mol-1 . The value of x/y is _________

[Use: Gas constant, R=8×10-2 L atm K-1 mol-1 ]

MEDIUM
Given the critical temperature and critical pressure of CO2 gas are 30°C and 72 atm respectively, find the approximate values of Van der Waals constants 'a' (in L2. atm. mol-2) and 'a' (in L. mol-1).
EASY

Among the following gases, the order of liquefiability is
a) SO2
b) CO2
c) CH4
d) NH3

EASY
For an ideal gas, the compressibility factor is
EASY
According to Andrews isothermal at what temperature the carbon dioxide gas starts to condense at 73 atmosphere?
HARD

The isotherms of a gas are shown below :

Question Image

Among the following,

(i) At T1, the gas cannot be liquefied

(ii) At point B, liquid starts to appear at T2

(ii) TC is the highest temperature at which the gas can be liquefied

(iv) At point A, a small increase in pressure condenses the whole system to a liquid

The correct statements are :

MEDIUM
A gas at 350 K and 15 bar has a molar volume 20 per cent smaller than that for an ideal gas under the same conditions. The correct option about the gas, and its compressibility factor Z is
EASY
A certain gas obeys PVm-b=RT. The value of ZPT is xbRT. The value of x is              (Integer answer) (Z : compressibility factor)
EASY
A gas such as carbon monoxide would be most likely to obey the ideal gas law at:
MEDIUM
Which of the following two gases can be cooled from temperature by the Joule-Thomson effect?
EASY

Which of the following gases can be absorbed in more proportion?

MEDIUM
The critical temperatures of four gases K,L,M and N are 154.3 K,5.3 K,33.2 K and 126 K respectively. Which of these gases will liquify first if they start cooling from 500 K to their critical temperatures?
MEDIUM
Consider the van der Waal's constants, a and b, for the following gases.
Gas Ar Ne Kr Xe
a/(atm dm6 mol-2) 1.3 0.2 5.1 4.1
b/(10-2 dm3 mol-1) 3.2 1.7 1.0 5.0

Which gas is expected to have the highest critical temperature?