Redox Reactions and Titration

IMPORTANT

Redox Reactions and Titration: Overview

This topic covers concepts, such as, Redox Reactions as a Basis for Titrations etc.

Important Questions on Redox Reactions and Titration

MEDIUM
IMPORTANT

KMnO4 acts as an oxidising agent in alkaline medium. When alkaline KMnO4 is treated with KI, iodide ion is oxidised to IOX-. The value of X is _____.

HARD
IMPORTANT

How many ml of 0.125 M Cr3+ must be reacted with 12.00 ml of 0.200 M MnO4- if the redox products are Cr2O72-and Mn2+?

HARD
IMPORTANT

25 ml  of household bleach solution was mixed with 30 ml of  0.50 M KI and 10 ml of  4 N acetic acid. In the titration of the liberated iodine, 48 ml of 0.25 N Na2S2O3 was used to reach the end point. The molarity of the household bleach solution is  

HARD
IMPORTANT

5 mLof 8 N nitric acid, 4.8 mL of 5 N hydrochloric acid and a certain volume of 17 M sulphuric acid are mixed together and made up to 2 L. 30 mL of this acid mixture exactly neutralise 42.9 mL of sodium carbonate solution containing one gram of Na2CO3.10H2O in 100 mL of water. Calculate the amount in grams of the sulphate ions in solution. Report the answer after multiplying with 10 and round off to the nearest integer.

MEDIUM
IMPORTANT

Conductometric titration curve of an equimolar mixture of HCl and HCN with NaOH (aq) is

MEDIUM
IMPORTANT

10 mL of H2O2 solution on treatment with KI and titration of liberated I2, required 10 mL of 1N hypo. Thus H2O2 is -

HARD
IMPORTANT

Acidified KMnO4 oxidises oxalic acid to CO2. What is the volume (in litres) of 10-4M KMnO4 required to completely oxidise 0.5 L of 10-2 M oxalic acid in acid medium?

MEDIUM
IMPORTANT

Amount of oxalic acid present in a solution can be determined by its titration with KMnO4 solution in the presence of H2SO4. The titration given unsatisfactory result when carried out in the presence of HCl because HCl

MEDIUM
IMPORTANT

The oxidation state of chromium in the final product formed by the reaction between KI and acidified potassium dichromate solution is

HARD
IMPORTANT

A mixture of FeO and Fe2O3 is completely reacted with 100 mL of 0.25 M acidified KMnO4 solution. The resultant solution was then titrated with zinc dust which converted Fe3+ of the solution to Fe2+. The Fe2+ required 1000 mL of 0.1 M K2Cr2O7 solution. Find out the percentage weight of Fe2O3 in the mixture.

EASY
IMPORTANT

Iodine oxidises S2O32- ion to

HARD
IMPORTANT

1.2 g of a salt with its empirical formula KxHy(C2O4)z was dissolved in 50 mL of water and its 10 mL portion required 11 mL of a 0.1 M HCl solution to reach the equivalence point. In a separate titration, 15 mL of the stock solution required 20 mL 0.2475 M KOH to reach the equivalence point. Determine the empirical formula of salt.

MEDIUM
IMPORTANT

1 M NaOH solution was slowly added into 1000 mL of 183.75 g impure H2SO4 solution and the following plot was obtained. The percentage purity of  H2SO4 sample and slope of the curve respectively are :


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