Enthalpies for Different Types of Reactions

IMPORTANT

Enthalpies for Different Types of Reactions: Overview

This topic covers concepts, such as, Enthalpy of Dilution, Lattice Enthalpy, Kirchhoff's Equation at Constant Pressure & Kirchhoff's Equation at Constant Volume etc.

Important Questions on Enthalpies for Different Types of Reactions

MEDIUM
IMPORTANT

From the data of following bond energies:

 HHbondenergy:431.37kJmol1C=Cbondenergy:606.10kJmol1CCbondenergy:336.49kJmol1CHbondenergy:410.50kJmol1

Calculate the enthalpy of the following reaction in kJmol1.

Question Image 

 

                               

EASY
IMPORTANT

Given that bond energies of HH  and  ClCl  are  430 kJmol1and240kJmol1respectively and ΔHf for HClis −90 kJmol1, bond enthalpy of HCl is:

                               

EASY
IMPORTANT

For which one of the following equations is ΔHreaction° equal to ΔHf° for the product?

                               

MEDIUM
IMPORTANT

What is the enthalpy change for,

2H2O2(l)2H2O(l)+O2(g) if heat of formation of  H2O2(l)  and  H2O(l)  are -188 and -286 kJ/molrespectively (in standard conditions)?

EASY
IMPORTANT

The values of heat of formation of  SO2​​ andSO3 are –298.2 kJ and –98.2 kJ. The enthalpy change of the reaction

 SO2+12O2SO3 will be

                               

EASY
IMPORTANT

Assume each reaction is carried out in an open container. For which reaction will ΔH=ΔE ?

                               

MEDIUM
IMPORTANT

The absolute enthalpy of neutralisation of the reaction:

 MgOs+2HClaqMgCl2aq+H2Ol will be:

[Consider the actual value instead of magnitude].

                               

EASY
IMPORTANT

For the reaction:

C3H8(g)+5O2(g)3CO2(g)+4H2O(l)

at constant temperature, ΔHΔE is:

                               

MEDIUM
IMPORTANT

Which one of the following is the correct relation between CP and CV for one mole of an ideal gas? (R is molar gas constant)

HARD
IMPORTANT

The standard enthalpy of formation of CH4g,CO2g and H2Ol are -75 kJ mol-1, -393 kJ mol-1 and -286 kJ mol-1 respectively. The amount of heat liberated (in kJ2) when 3.2 g of methane gas is burnt under standard conditions is

MEDIUM
IMPORTANT

2 moles of a mixture of acetylene and ethane produced on combustion, 5500 kJ of heat energy. The enthalpies of combustion of acetylene and ethane are 2000 and 3000 kJ mol-1 respectively. The ratio of acetylene to ethane in the mixture is

EASY
IMPORTANT

How many of the following have standard heat of formation value of zero.

(i) Br2l

(ii) CO2g

iii C(graphite) 

(iv) Cl2l

(v) Cl2g

(vi) F2g

(vii) Fg

(viii) I2g

ix S(monoclinic )

x N2(g)

(xi) Pblcak

(xii) Pred

(xiii) CH4

MEDIUM
IMPORTANT

In Kirchhoff's equation, the term Cv is used instead of Cp at constant volume.

MEDIUM
IMPORTANT

Kirchhoff's equation at constant volume is : 

MEDIUM
IMPORTANT

The variation of U with temperature is expressed by Kirchoff's equation.

MEDIUM
IMPORTANT

Temperature affects the  enthalpy change of a reaction.

HARD
IMPORTANT

Write the Kirchhoff's equation at constant volume and at constant pressure.

HARD
IMPORTANT

Specific heat capacity is not the parameter that is used to relate the enthalpy of a reaction and temperature.

MEDIUM
IMPORTANT

Describe the effect of temperature on enthalpy of reaction.

MEDIUM
IMPORTANT

What happens to the enthalpy of the system if its temperature increases?