Stereochemical Aspects of Nucleophilic Substitution Reactions of Haloalkanes and Haloarenes

Author:Embibe Experts
JEE Main/Advance
IMPORTANT

Important Questions on Stereochemical Aspects of Nucleophilic Substitution Reactions of Haloalkanes and Haloarenes

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IMPORTANT

The enantiomeric excess and observed rotation of a mixture containing 6 gm of  (+)-2 -butanol and 4gm of (-)-2 -butanol are respectively (If the specific rotation of enantiomerically pure (+)-2- butanol is +13.5 unit).

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IMPORTANT

The number of chiral carbon atoms in the compound W, X , Y and Z respectively would be

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HARD
IMPORTANT

Which configuration will be adopted by the product at carbon atoms marked (1) and (2), respectively, in the given reaction?

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Cyclohexene reacts with limited amount of bromine in the presence of light to form product XC6H9Br. The correct statement about X is 

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An enantiomerically pure acid is treated with racemic mixture of an alcohol having one chiral carbon. The ester formed will be