Werner's Theory of Coordination Compounds

$2.33 \mathrm{g}$ of compound $\mathrm{X}$ (empirical formula ${\mathrm{CoH}}_{12}{\mathrm{N}}_4{\mathrm{Cl}}_3$) upon treatment with excess ${\mathrm{AgNO}}_3$ solution produces $1.435 \mathrm{g}$ of a white precipitate. The primary and secondary valences of cobalt in compound $\mathrm{X}$, respectively, are [Given : Atomic mass: $\mathrm{Co}=59,\mathrm{Cl}=35.5,\mathrm{Ag}=108$]

The number of ions produced in water by dissolution of the complex having the empirical formula, ${\mathrm{CoCl}}_3 4{\mathrm{NH}}_3$ is:

Which of the following is correct for both the following coordination compounds?

$\left(\mathrm{I}\right) {\mathrm{CoCl}}_3·6{\mathrm{NH}}_3$ and

$\left(\mathrm{II}\right) {\mathrm{PtCl}}_4·5{\mathrm{NH}}_3$

Consider the following statements:

According to Werner's theory:

(1) Ligands are connected to the metal ions by ionic bonds.

(2) Secondary valencies have directional properties

(3) Secondary valencies are non-ionisable

Of these statements:

${\mathrm{CoCl}}_3·4{\mathrm{H}}_2\mathrm{O}$ is an anhydrous binary solute hence, its Werner's representation is:

The number of ions given by $\left[\mathrm{Co}{\left({\mathrm{NH}}_3\right)}_6\right]{\mathrm{Cl}}_3$ in aqueous solution is _____.

Which of the following is TRUE about secondary valence?

According to Werner's theory, the most metallic elements exhibit _____ types of valence(s).

The primary valency of iron in ${\mathrm{K}}_4\left[\mathrm{Fe}(\mathrm{CN}{)}_6\right]$ is

According to the postulates of Werner for coordination compounds,

Which one is the most likely structure of ${\mathrm{CrCl}}_3·6{\mathrm{H}}_2\mathrm{O}$, if $\raisebox{1ex}{$1$}\!\left/ \!\raisebox{-1ex}{$3$}\right.$ of the total chlorine in the compound is precipitated by adding ${\mathrm{AgNO}}_3$?

One mole of the complex compound $\mathrm{Co}{\left({\mathrm{NH}}_3\right)}_5{\mathrm{Cl}}_3$ gives $3$ moles of ions on dissolution in water. One mole of the same complex reacts with two moles of ${\mathrm{AgNO}}_3$ solution to yield two moles of $\mathrm{AgCl}$$\left(\mathrm{s}\right)$. The structure of the complex is:

Pick out a poor electrolytic conductor in solution, from among the following:

Primary and secondary valency of $\mathrm{Pt}$ in $\left[\mathrm{Pt}\left(\mathrm{en}\right){}_2{\mathrm{Cl}}_2\right]{\mathrm{Cl}}_2$ are

The moles of $\mathrm{AgCl}$ precipitated per mole of the following complex, respectively, are $0, 2, 1$ and $2$.

$\left(\mathrm{i}\right)$ ${\mathrm{PtCl}}_2·2{\mathrm{NH}}_3$

$\left(\mathrm{ii}\right)$ ${\mathrm{NiCl}}_2·6{\mathrm{H}}_2\mathrm{O}$

$\left(\mathrm{iii}\right)$ ${\mathrm{CoCl}}_3·4{\mathrm{NH}}_3$

$\left(\mathrm{iv}\right)$ ${\mathrm{PdCl}}_2·4{\mathrm{NH}}_3$

Based on the above information, the secondary valency of:

$\left(\mathrm{a}\right)$ Platinum is $4$       $\left(\mathrm{b}\right)$ Cobalt is $6$

$\left(\mathrm{c}\right)$ Nickel is $2$            $\left(\mathrm{d}\right)$ Palladium is $4$

On adding potassium ferrocyanide to any ferric salt, a Prussian blue colour is obtained. The number of ions produced by ionization of this Prussian blue complex in the solution is:

The coordination number of metal $\mathrm{M}$ in a complex having a molecular formula ${\mathrm{MCl}}_3\mathbf{·}4{\mathrm{H}}_2\mathrm{O}$ is $6$ and there is no molecule of water of crystallization in it. The volume of $0.1 \mathrm{M} {\mathrm{AgNO}}_3$ solution needed to precipitate the free chloride ions is $200 \mathrm{mL}$ of $0.01 \mathrm{M}$. Then, the complex is:

A solution containing $0.319 \mathrm{g}$ of ${\mathrm{CrCl}}_3\mathbf{·}6{\mathrm{H}}_2\mathrm{O}$ was passed through cation-exchange resin and the acid coming out of the exchange resin consumed $28.5 \mathrm{mL}$ of $0.125 \mathrm{M} \mathrm{NaOH}$ solution. The formula of the complex is:

(Molecular weight of the complex is $266.7$)

The ratio of the primary valency and the secondary valency of the metal ion in the coordination compound ${\mathrm{K}}_2\left[\mathrm{Ni}{\left(\mathrm{CN}\right)}_4\right]$ is: 

If an excess of ${\mathrm{AgNO}}_3$ solution is added to $100 \mathrm{mL}$ of $0.024 \mathrm{M}$ solution of dichloridobis (ethylenediamine) cobalt $\left(\mathrm{III}\right)$ chloride, how many moles of $\mathrm{AgCl}$ are precipitated?