Gibbs Free Energy or Gibbs Function

Author:Embibe Experts
MHT-CET
IMPORTANT

Important Questions on Gibbs Free Energy or Gibbs Function

MEDIUM
IMPORTANT

Given, ΔG°=-nFEcell ° and ΔG°=-RT ln k. The value of n=FRT will be given by the slope of which line in the figureQuestion Image

HARD
IMPORTANT

The densities of graphite and diamond at 298 K are 2.25 and 3.31 g cm-3, respectively. If the standard free energy difference ΔG° is equal to 1895 J mol-1, the pressure at which graphite will be transformed into diamond at 298 K is

HARD
IMPORTANT

The factor of ΔG values is important in metallurgy. The ΔG values for the following reactions at 800°C are given as:

S2 s+2O2 g2SO2 g; ΔG=-544 kJ
2Zn s+S2 s2ZnS s; ΔG=-293 kJ
2Zn s+O2 g2ZnO s; ΔG=-480 kJ

ΔG for the below reaction will be

2ZnS s+3O2 g2ZnO s+2SO2 g

HARD
IMPORTANT

Match List I (Equations) with List II (Types of process) and select the correct option.

List-I
(Equations)
List-II
(Types of process)
A. Kp>Q 1.

Non-spontaneous

B. ΔG°<RT ln Q 2.

Equilibrium

C. KP=Q 3. Spontaneous and endothermic
D. T>ΔHΔS 4. Spontaneous

MEDIUM
IMPORTANT

What is the free energy change for the conversion of 1 mole of water into steam at 373.2 K. The heat of vaporization Hv of water at 373.2 K is 9.1 kcal mol-1. The entropy change is 25.5 cal mol-1 K-1.

EASY
IMPORTANT

In an irreversible process taking place at constant T and P and in which only the pressure-volume work is being done, the change in Gibbs free energy (dG) and the change in entropy (dS) satisfy the criteria

MEDIUM
IMPORTANT

A certain reaction is non-spontaneous at 298 K. The entropy change during the reaction is 121 J K-1. Is the reaction endothermic or exothermic? The minimum value of ΔH for the reaction is

EASY
IMPORTANT

What is the free energy change ΔG when 1.0 mol of water at 100°C and 1 atm pressure is converted into steam at 100°C and 1 atm pressure?

EASY
IMPORTANT

Identify the correct statement for the change of Gibbs energy for a system (ΔGsystem ) at constant temperature and pressure.

EASY
IMPORTANT

The enthalpy and entropy change for the reaction Br2 I+Cl2 g2BrCl g are 30 kJ mol-1 and 105 J K-1 mol-1, respectively. The temperature at which the reaction will be in equilibrium is

EASY
IMPORTANT

The standard enthalpy and standard entropy changes for the oxidation of ammonia at 298 K are -382.64 kJ mol-1 and -145.6 J K-1 mol-1, respectively. The standard Gibbs energy change for the same reaction at 298 K is

EASY
IMPORTANT

Standard Gibbs free energy change for isomerisation reaction cis-2 pentene trans-2 pentene is -3.67 kJ/mol at 400 K. If more trans-2 pentene is added to the reaction vessel,