Andhra Pradesh Board Solutions for Chapter: Organic Compounds Containing Nitrogen, Exercise 4: Intext Questions

Arrange the following in increasing order of their basic strength:

 ${\mathrm{C}}_2{\mathrm{H}}_5{\mathrm{NH}}_2, {\mathrm{C}}_6{\mathrm{H}}_5{\mathrm{NH}}_2, {\mathrm{NH}}_3, {\mathrm{C}}_6{\mathrm{H}}_5{\mathrm{CH}}_2{\mathrm{NH}}_2$ and ${\left({\mathrm{C}}_2{\mathrm{H}}_5\right)}_2\mathrm{NH}$

Arrange the following in increasing order of their basic strength:

 ${\mathrm{C}}_2{\mathrm{H}}_5{\mathrm{NH}}_2, {\left({\mathrm{C}}_2{\mathrm{H}}_5\right)}_2\mathrm{NH}, {\left({\mathrm{C}}_2{\mathrm{H}}_5\right)}_3\mathrm{N}, {\mathrm{C}}_6{\mathrm{H}}_5{\mathrm{NH}}_2$.

Arrange the following in increasing order of their basic strength:

${\mathrm{CH}}_3{\mathrm{NH}}_2, {\left({\mathrm{CH}}_3\right)}_2\mathrm{NH}, {\left({\mathrm{CH}}_3\right)}_3\mathrm{N}, {\mathrm{C}}_6{\mathrm{H}}_5{\mathrm{NH}}_2, {\mathrm{C}}_6{\mathrm{H}}_5{\mathrm{CH}}_2{\mathrm{NH}}_2.$

Complete the following acid-base reaction and name the product:

${\mathrm{C}\mathrm{H}}_3{\mathrm{C}\mathrm{H}}_2{\mathrm{C}\mathrm{H}}_2{\mathrm{N}\mathrm{H}}_2+\mathrm{H}\mathrm{C}\mathrm{l}⟶$

Complete the following acid-base reaction and name the product:

${\left({\mathrm{C}}_2{\mathrm{H}}_5\right)}_3\mathrm{N}+\mathrm{H}\mathrm{C}\mathrm{l}\to$

Write reactions of the final alkylation product of aniline with excess of methyl iodide in the presence of sodium carbonate solution.

Write chemical reaction of aniline with benzoyl chloride and write the name of the product obtained.

Write structures of different isomers corresponding to the molecular formula, ${\mathrm{C}}_3{\mathrm{H}}_9\mathrm{N}$. Write IUPAC names of the isomers which will liberate nitrogen gas on treatment with nitrous acid.