Law of Equipartition of Energy

Author:Himachal Pradesh Board
11th Himachal Pradesh Board
IMPORTANT

Law of Equipartition of Energy: Overview

This topic discusses the example of two independent axes of rotation of a diatomic molecule. The law of equipartition of energy is illustrated with formulas and derivation here.

Important Questions on Law of Equipartition of Energy

MEDIUM
IMPORTANT

A gas in equilibrium has uniform density and pressure throughout its volume. This is strictly true only if there are no external influences. A gas column under gravity, for example, does not have uniform density (and pressure). As you might expect, its density decreases with height. The precise dependence is given by the so-called law of atmospheres

n2=n1exp-mgh2-h1/kBT
where n2, n1 refer to number density at heights h2 and h1 respectively. Use this relation to derive the equation for sedimentation equilibrium of a suspension in a liquid column:
n2=n1exp-mgNAρ-ρ'h2-h1/(ρRT)
where ρ is the density of the suspended particle, and ρ' that of the surrounding medium.
[ NA is Avogadro’s number, and R the universal gas constant.]

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IMPORTANT

From a certain apparatus, the diffusion rate of hydrogen has an average value of 28.7 cm3s1. The diffusion of another gas under the same conditions is measured to have an average rate of 7.2 cm3s1. Identify the gas. [Hint: Use Graham’s law of diffusion: R1/R2=M2M11/2, where R1,R2 are diffusion rates of gases 1 and 2, and M1 and M2 their respective molecular masses. The law is a simple consequence of kinetic theory.]

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A metre long narrow bore held horizontally (and closed at one end) contains a 76 cm long mercury thread, which traps a 15 cm column of air. What happens if the tube is held vertically with the open end at the bottom?

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Estimate the average thermal energy of a helium atom at (i) room temperature (27 °C), (ii) the temperature on the surface of the Sun (6000 K), (iii) the temperature of 10million Kelvin (the typical core temperature in the case of a star).