In a certain gaseous reaction between A and B , A + 3 B → AB 3 . The initial rates are reported as follows: [A] [B] Initial rate 0 . 1 M 0 . 2 M 0 . 3 M 0 . 4 M 0 . 1 M 0 . 1 M 0 . 2 M 0 . 3 M 0 . 002 Ms - 1 0 . 002 Ms - 1 0 . 008 Ms - 1 0 . 018 Ms - 1 Which of the following statement(s) is/are correct?

The overall order of the reaction is 2 and is zero order with respect to [ A ] .

The rate law is ⇒ r = k [ A ] 0 [ B ] 3 .

The overall order of the reaction is 3 and it is of 3 rd order with respect to [ B ] .

The bromination of acetone that occurs in acid solution is represented by CH 3 COCH 3 ( aq ) + Br 2 ( aq ) → H + CH 3 COCH 2 Br 2 ( aq ) + HBr ( aq ) Given, Experiment Initial concentrations, M Initial rate of disappearance of Br 2 , M s - 1 Br 2 CH 3 COCH 3 H + 1 0 . 050 0 . 30 0 . 050 6 × 10 - 5 2 0 . 10 0 . 30 0 . 050 6 × 10 - 5 3 0 . 10 0 . 30 0 . 10 1 . 2 × 10 - 4 4 0 . 20 0 . 60 0 . 10 2 . 4 × 10 - 4 Based on the above data, the ones which do not represent rate law are

dx dt = k CH 3 COCH 3 Br 2 H + 2

Seema Saini Solutions for Chapter: Chemical Kinetics, Exercise 4: DPP 4.4

Author:Seema Saini

Seema Saini Chemistry Solutions for Exercise - Seema Saini Solutions for Chapter: Chemical Kinetics, Exercise 4: DPP 4.4

Attempt the free practice questions on Chapter 4: Chemical Kinetics, Exercise 4: DPP 4.4 with hints and solutions to strengthen your understanding. Chapterwise/Topicwise Daily Practice Problems (DPP) Physical Chemistry Part - 2 JEE Main & Advanced solutions are prepared by Experienced Embibe Experts.

Questions from Seema Saini Solutions for Chapter: Chemical Kinetics, Exercise 4: DPP 4.4 with Hints & Solutions

MEDIUM

JEE Main

IMPORTANT

Chapterwise/Topicwise Daily Practice Problems (DPP) Physical Chemistry Part - 2 JEE Main & Advanced>Chapter 4 - Chemical Kinetics>DPP 4.4>Q 9

For the non-stoichiometric reaction, $2 A + B \to C + D$ , the following kinetic data were obtained in three separate experiments, all at $298 K$ .

Initial concentration of $A$	Initial concentration of $B$	Initial rate of formation of $C$
$0.1 M$	$0.1 M$	$1.2 \times 10^{- 3} M s^{- 1}$
$0.1 M$	$0.2 M$	$1.2 \times 10^{- 3} M s^{- 1}$
$0.2 M$	$0.1 M$	$2.4 \times 10^{- 3} M s^{- 1}$

The rate law for the formation of $C$ is

MEDIUM

JEE Main

IMPORTANT

Chapterwise/Topicwise Daily Practice Problems (DPP) Physical Chemistry Part - 2 JEE Main & Advanced>Chapter 4 - Chemical Kinetics>DPP 4.4>Q 10

The data for the reaction; $A + B \overset{k}{⟶} C$ are,

Experiment	$[A]_{0} M$	$[B]_{0} M$	Initial rate $(M s^{- 1})$
$1$	$0.012$	$0.035$	$0.10$
$2$	$0.024$	$0.070$	$0.80$
$3$	$0.024$	$0.035$	$0.10$
$4$	$0.012$	$0.070$	$0.80$

The rate law corresponding to the above data is

HARD

JEE Main

IMPORTANT

Chapterwise/Topicwise Daily Practice Problems (DPP) Physical Chemistry Part - 2 JEE Main & Advanced>Chapter 4 - Chemical Kinetics>DPP 4.4>Q 11

For a hypothetical reaction $A + B \to C$ , suggest the order from the following data.

Experiment	$[A] (mol L^{- 1})$	$[B] (mol L^{- 1})$	Rate of reaction $(mol L^{- 1} s^{- 1})$
$I$	$0.25$	$0.25$	$3.0 \times 10^{- 3}$
$II$	$0.50$	$0.25$	$6.0 \times 10^{- 3}$
$III$	$0.50$	$0.50$	$1.20 \times 10^{- 2}$

HARD

JEE Main

IMPORTANT

Chapterwise/Topicwise Daily Practice Problems (DPP) Physical Chemistry Part - 2 JEE Main & Advanced>Chapter 4 - Chemical Kinetics>DPP 4.4>Q 12

In a certain gaseous reaction between $A$ and $B, A + 3 B \to {AB}_{3}$ . The initial rates are reported as follows:

[A]

[B]

Initial rate

$0.1 M$

$0.2 M$

$0.3 M$

$0.4 M$

$0.1 M$

$0.2 M$

$0.3 M$

$0.002 {Ms}^{- 1}$

$0.008 {Ms}^{- 1}$

$0.018 {Ms}^{- 1}$

Which of the following statement(s) is/are correct?

MEDIUM

JEE Main

IMPORTANT

Chapterwise/Topicwise Daily Practice Problems (DPP) Physical Chemistry Part - 2 JEE Main & Advanced>Chapter 4 - Chemical Kinetics>DPP 4.4>Q 13

Select the incorrect statements regarding the law that corresponds to data shown for the following reaction
$A + B \to Products$ .

Experiment	$[A]$	$[B]$	Rate
$1$	$0.012$	$0.035$	$0.1$
$2$	$0.024$	$0.070$	$0.8$
$3$	$0.024$	$0.035$	$0.1$
$4$	$0.012$	$0.070$	$0.8$

MEDIUM

JEE Main

IMPORTANT

Chapterwise/Topicwise Daily Practice Problems (DPP) Physical Chemistry Part - 2 JEE Main & Advanced>Chapter 4 - Chemical Kinetics>DPP 4.4>Q 14

$A + B \to C$

Experiment	$[A]$	$[B]$	Rate
$1$	$1.0$	$1.0$	$0.25$
$2$	$2.0$	$1.0$	$0.50$
$3$	$1.0$	$2.0$	$0.25$

Rate is expressed in $mol L^{- 1} \min^{- 1}$

Select the incorrect options regarding the order.

HARD

JEE Main

IMPORTANT

Chapterwise/Topicwise Daily Practice Problems (DPP) Physical Chemistry Part - 2 JEE Main & Advanced>Chapter 4 - Chemical Kinetics>DPP 4.4>Q 15

For the chemical reaction,

$A + B + C \to E$

The rate of reaction is doubled when the concentration of $B$ is doubled, and when the concentration of both $A$ and $B$ is doubled, the rate becomes doubled and when the concentration of both $B$ and $C$ are doubled the rate becomes quadrupled.

Which of the given statement(s) is/are correct?

HARD

JEE Main

IMPORTANT

Chapterwise/Topicwise Daily Practice Problems (DPP) Physical Chemistry Part - 2 JEE Main & Advanced>Chapter 4 - Chemical Kinetics>DPP 4.4>Q 16

The bromination of acetone that occurs in acid solution is represented by

${CH}_{3} {COCH}_{3} (aq) + {Br}_{2} (aq) \overset{H^{+}}{\to} {CH}_{3} {COCH}_{2} {Br}_{2} (aq) + HBr (aq)$

Given,

Experiment	Initial concentrations, $M$			Initial rate of disappearance of ${Br}_{2}, M s^{- 1}$
	$[{Br}_{2}]$	$[{CH}_{3} {COCH}_{3}]$	$[H^{+}]$
$1$	$0.050$	$0.30$	$0.050$	$6 \times 10^{- 5}$
$2$	$0.10$	$0.30$	$0.050$	$6 \times 10^{- 5}$
$3$	$0.10$	$0.30$	$0.10$	$1.2 \times 10^{- 4}$
$4$	$0.20$	$0.60$	$0.10$	$2.4 \times 10^{- 4}$

Based on the above data, the ones which do not represent rate law are

Seema Saini Solutions for Chapter: Chemical Kinetics, Exercise 4: DPP 4.4

Seema Saini Chemistry Solutions for Exercise - Seema Saini Solutions for Chapter: Chemical Kinetics, Exercise 4: DPP 4.4

Questions from Seema Saini Solutions for Chapter: Chemical Kinetics, Exercise 4: DPP 4.4 with Hints & Solutions

Learn and Prepare for any exam you want !