HARD
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For which of the following gases, the value of Z is greater than 1 at all pressures and at 273 K?

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Important Questions on States of Matter: Gaseous and Liquid States

EASY
A gas such as carbon monoxide would be most likely to obey the ideal gas law at:
EASY
In the following compressibility factor (Z) vs pressure graph at 300 K, the compressibility of CH4 at pressure < 200 bar deviates from ideal behavior because

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MEDIUM

The volume of gas A is twice than that of gas B. The compressibility factor of gas A is thrice than that of gas B at same temperature. What are the pressures of the gases for equal number of moles?

MEDIUM

The variation of the compressibility factor (Z) with pressure (P in bar) for some gases, are shown in the figure below. Identify the gases (A),(B) and (C).

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MEDIUM
Which of the following gases has high Boyle's temperature?
HARD

A gas has a compressibility factor of 0.5 and a molar volume of 0.4 dm3 mol-1 at a temperature of 800 K and pressure x atm. If it shows ideal gas behaviour at the same temperature and pressure, the molar volume will be  y dm3 mol-1 . The value of x/y is _________

[Use: Gas constant, R=8×10-2 L atm K-1 mol-1 ]

HARD

The isotherms of a gas are shown below :

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Among the following,

(i) At T1, the gas cannot be liquefied

(ii) At point B, liquid starts to appear at T2

(ii) TC is the highest temperature at which the gas can be liquefied

(iv) At point A, a small increase in pressure condenses the whole system to a liquid

The correct statements are :

EASY
A certain gas obeys PVm-b=RT. The value of ZPT is xbRT. The value of x is              (Integer answer) (Z : compressibility factor)
EASY
The compressibility factor (Z) of a gas is <1 at STP. Therefore
HARD
Which one of the following plots is correct for the behaviour of ideal and real gases?
MEDIUM
A gas at 350 K and 15 bar has a molar volume 20 per cent smaller than that for an ideal gas under the same conditions. The correct option about the gas, and its compressibility factor Z is
MEDIUM
The pressure p and volume V isotherm of a van der Waals' gas, at the temperature at which it undergoes gas to liquid transition, is correctly represented by
MEDIUM
The internal energy per mole of an ideal gas is denoted by Eideal. The same for a real gas obeying van der Waals equation is Ereal. Assuming the average kinetic energy of the molecules of the two gases at the same temperature to be equal, the correct statement for the gas at low pressure is
HARD
What is meant by molar volume of a gas? Mention two reasons for deviation of real gases from the behaviour of ideal gases?
MEDIUM

Among the gases a, b, c, d, e and f, the gases that show only positive deviation from ideal behavior at all pressures in the graph are

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HARD
For one mole of a van der Waals' gas, the compressibility factor Z=pVRT at a fixed volume will certainly decrease, if
[Given : " a " and " b " are standard parameters for van der Waals' gas]
 
HARD
If Z is the compressibility factor, then Van der Waal's equation at low pressure can be written as: