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What is the difference between volatile and non-volatile ?

Important Questions on Organic Chemistry- Some Basic Principles and Techniques

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In which of the following compounds, the C-Cl bond ionization shall give most stable carbonium ion?
HARD
A solution of (-)1-chloro-1-phenylethane in toluene racemises slowly in the presence of a small amount of SbCl5, due to the formation of :
MEDIUM
The hyperconjugative stabilities of tert-butyl cation and 2-butene, respectively, due to