EASY
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A certain metal salt solutions is electrolysed in series with a silver coulometer. The weights of silver and the metal deposited are 0.5094 g and 0.2653 g. Calculate the valency of the metal if its atomic weight is nearly that of silver.

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Important Questions on Electrochemistry

EASY
Two Faraday of electricity is passed through a solution of CuSO4 . The mass of copper deposited at the cathode is: (Atomic mass of Cu = 63.5 amu)
HARD

A steady current of 2 amperes was passed through two electrolytic cells X and Y connected in series containing electrolytes FeSO4 and ZnSO4 until 2.8 g of Fe deposited at the cathode of cell X. How long did the current flow ? Calculate the mass of Zn deposited at the cathode of cell Y.

( Molar mass :Fe=56 g mol-1   Zn=65.3 g mol-1  , 1F=96500 C mol-1 )

EASY
The number of moles of electrons passed when a current of 2A is passed through a solution of electrolyte for 20 minutes is
MEDIUM
A constant current (0.5 amp) is passed for 1 hour through (i) aqueous AgNO3 . (ii) aqueous CuSO4 and (iii) molten AlF3 , separately. The ratio of the mass of the metals deposited on the cathode is [MAg, MCu, MAl are molar masses of the respective metals]
MEDIUM
Calculate the number of coulombs required to deposit 40.5 g of Al when the electrode reaction is Al3++3e- Al(s).
MEDIUM
When an electric current is passed through acidified water, 112 mL of hydrogen gas at N.T.P was collected at the cathode in 965 seconds. The current passed, in ampere, is:
HARD

A solution of copper sulphate electrolysed for 20 minute with a current of 1.5 Ampere. Calculate the mass of copper deposited at the cathode. F = 96500 C

EASY
For electroplating, 1.5 amp current is passed for 250 s through 250 mL of 0.15 M solution of MSO4. Only 85% of the current was utilised for electrolysis. The molarity of MSO4 solution after electrolysis is closest to [Assume that the volume of the solution remain constant]
EASY
State Faraday's first law of electrolysis.
EASY
State Faraday's second law of electrolysis.
MEDIUM
When 9.65 ampere current was passed for 1.0 hour into nitrobenzene in acidic medium, the amount of p-aminophenol produced is:
EASY
The quantity of electricity needed to separately electrolyse 1 M solution of ZnSO4, AlCl3 and AgNO3 completely is in the ratio of
EASY
During the electrolysis of molten sodium chloride, the time required to produce 0.10 mol of chlorine gas using a current of 3 amperes is
MEDIUM
The anodic half-cell of lead-acid battery is recharged using electricity of 0.05 Faraday. The amount of PbSO4  electrolyzed in g during the process is: (Molar mass of PbSO4=303g mol-1)
EASY
The number of electrons delivered at the cathode, during electrolysis by a current of 1 ampere in 60 seconds is (charge on electron =1.60×10-19 C)
EASY
The density of metal and equivalent weight of a metal are 10.5 g cm-3 and 100, respectively. The time required for a current of 3amp to deposit a 0.005mm thick layer of the same metal on an area of 80cm2 is closest to
HARD
Calculate the molarity of a solution containing 5g of NaOH dissolved in the product of a H2-O2 fuel cell operated at 1A current for 595.1 hours.

(Assume 1F=96500 C/mol of electrons and molecular weight of NaOH as 40g mol-1 )
MEDIUM
Give reason: On the basis of E values, O2 gas should be liberated at anode but it is Cl2 gas which is liberated during electrolysis of aqueous NaCl.
MEDIUM
A solution of NiNO32 is electrolyzed between platinum electrodes using a current of 5 amperes for 20 minutes. What mass of Ni is deposited at the cathode?
EASY
A solution of NiNO32 is electrolyzed between platinum electrode 0.1 Faraday electricity. How many mole of Ni will be deposited at the cathode?