HARD
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A gas expands in volume from 2L to 5L against a pressure of 1 atm at constant temperature. The work done by the gas will be

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Important Questions on Chemical Thermodynamics

HARD
What will be the enthalpy of reaction  2NO+O22NO2 from the given formation enthalpy values ? The standard enthalpy of formation values for O2, NO and NO2 are as follows: O2(g):0 kJ/mol, NO(g):90.25 kJ/mol and NO2(g)33.18 kJ/mol respectively.
EASY
Calculate the work done during the reactions represented by the following thermochemical equation at 300 K:
CH4g +2O2gCO2g+2H2Ol
R=8.314 JK-1mol-1
EASY
Which of the following relation is not correct?
MEDIUM
The standard enthalpy of vaporisation Δvap H°, for water at 100°C is 40.66 kJ mol-1. The internal energy of vaporisation of water at 100°C (in kJmol-1 ) is (assume water vapour to behave like an ideal gas)
EASY

For which of the following systems, the difference between ΔH and ΔU is not significant?

(i) Solids

(ii) Gases

(iii) Mixture of gases and liquids

(iv) Liquids

EASY
Consider the following reaction: CaOs+CO2gCaCO3s. The reaction is spontaneous at low temperature because
MEDIUM

A fish swimming in water body when taken out from the water body is covered with a film of water of weight 36 g. When it is subjected to cooking at 100 °C, then the internal energy for vaporization in kJmol-1 is integer]

[Assume steam to be an ideal gas. Given ΔvapH for water at 373 K and 1 bar is 41.1 kJ mol-1:R=8.31 J K-1 mol-1]

MEDIUM
The qualitative sketches I, II and III given below show the variation of surface tension with molar concentration of three different aqueous solutions of KCl, CH3OH  and CH3CH211OSO3- Na+ at room temperature. The correct assignment of the sketches is -

Question Image
MEDIUM
2 moles of a monoatomic ideal gas at 25oC is heated reversibly at a constant pressure of 2 atm to reach a final temperature of 125oC. Calculate the ΔH. Cv=32R
MEDIUM
A better criterion for ideality of a gas than UVT=0 is
EASY
Which of the following process best describes atomization of CH4g?
EASY
Two moles on an ideal gas is expanded isothermally and reversibly at 300 K form 1 L to 10 L. The enthalpy change in KJ is
HARD

Calculate the work done in the following reaction at 50°C. State whether work is done on the system or by the system.

SO2g+12O2gSO3g

EASY
Find the approximate value of (ΔH-ΔU) in J·mol-1, for the formation of CO from its elements at 298 K. R=8.314 J·K-1 mol-1
EASY
A piece of ice falls from a height h so that it melts completely. Only one-quarter of the heat produced is absorbed by the ice and all energy of ice gets converted into heat during its fall. The value of h is:
(Latent heat of ice is 3.4Ɨ105 J kg-1 and g=10 N kg-1)
MEDIUM

The combination of plots which does not represent isothermal expansion of an ideal gas is

(A) Question Image

(B) Question Image

C Question Image

(D) Question Image

HARD
An ideal gas undergoes isothermal compression from 5 m3 to 1 m3 against a constant external pressure of 4 N m-2. The heat released in this process is 24 J mol-1K-1 and is used to increase the pressure of 1 mole of Al. The temperature of Al increases by:
EASY
For the formation of NH3( g) from its constituent elements at constant temperature and presssure, which of the following options is correct
MEDIUM

The internal energy change (in J) when 90 g of water undergoes complete evaporation at 100°C is ..............

(Given : ΔHvap for water at 373 K=41 kJ/molR=8.314 JK-1 mol-1)

MEDIUM
Identify the equation in which change in enthalpy is equal to change in internal energy