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A graph between log t1/2 vs log a, with a being the initial concentration of A in the reaction A Product, is shown in the figure. 

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Then the rate law is

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Important Questions on Chemical Kinetics

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Which of the following is incorrect?
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Assuming gas-phase decomposition of dimethyl ether follows 1st order kinetics:

CH3-O-CH3 (g)CH4 (g)+H2 (g)+CO (g) 

The reaction is carried out in a constant volume container at 500°C and has a half-life 14.5 min. Initially, only dimethyl ether is present at a pressure of 0.4 atm. The total pressure of the system after 12 min is: (given log1.8 = 0.249)

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Addition of a catalyst at 300 K increases the rate of a chemical reaction by a factor of 36. By how many kJ the activation energy of the catalysed pathway is less than the activation energy of the original pathway approximately log 6=0.78 and R=8.3 J k-1mol-1.
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A first order reaction is 50% completed in 20 minutes at 27°C and in 5 minutes at 47°C. The energy of activation of the reaction is
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The increase in the rate constant of a reaction when its temperature is increased from 298 K to 308 K is nearly: Ea=12.68 kcal mol-1, log 2=0.302
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The rate constant is doubled when temperature increases from 27 °C to 37 °C. Activation energy in kJ is:
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What is the order with respect to [A], [B] and [C], respectively?
 
[A] [B] [C] Rate M/sec
0.2 0.1 0.02 8.08 × 103
0.1 0.2 0.02 2.01 × 103
0.1 1.8 0.18 6.03 × 103
0.2 0.1 0.08 6.464 × 102
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IMPORTANT
The half-life period of a first-order chemical reaction is 6.93 minutes. The time required for the completion of 99% of the chemical reaction will be log2=0.301