EASY
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A process in which the amount of heat supplied to the system goes fully to change its internal energy and temperature is

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Important Questions on Thermodynamics

MEDIUM
Five moles of an ideal gas at 293 K is expanded isothermally from an initial pressure of 2.1 MPa to 1.3 MPa against at constant external pressure 4.3 MPa. The heat transferred in this process is ___ kJmol-1. (Rounded-off to the nearest integer)

[ Use R=8.314 J mol-1 K-1]

EASY

How much heat will be absorbed by 1 mole of an ideal gas, if it is expanded reversibly from 5 L to 25 L at 27oC

(log 3=0.5, log 4=0.6, log 5=0.7)

MEDIUM
An ideal gas initially at temperature, pressure and volume, 27°C,1.00 bar and 10 L respectively is heated at constant volume until pressure is 10.0 bar, it then undergoes a reversible isothermal expansion until pressure is 1.00bar, what is the total work W, during this process?
EASY

One mole of an ideal gas at 27 °C is taken from A to B as shown in the given PV indicator diagram. The work done by the system will be _______ ×10-1 J. [Given, R=8.3 J mole-1 K, ln2=0.6931] (Round off to the nearest integer)

(Round off to the nearest integer)

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EASY
If 100 mole of H2O2 decompose at 1 bar and 300 K, the work is done (kJ) by one mole of O2(g) as it expands against 1 bar pressure is:

2H2O2l2H2Ol+O2(g)

R=8.3 J K-1 mol-1
HARD

At 25°C,50 g of iron reacts with HCl to form FeCl2. The evolved hydrogen gas expands against a constant pressure of 1 bar. The work done by the gas during this expansion is -_______ J.

(Round off to the Nearest Integer)

[Given : R=8.314 J mol-1 K-1. Assume, hydrogen is an ideal gas]

[Atomic mass off Fe is 55.85 u]

HARD
During the free expansion of an ideal gas in an isolated chamber,
 
HARD
Write the conditions for maximum work done by the system.
MEDIUM

The magnitude of work done by a gas that undergoes a reversible expansion along the path ABC shown in the figure is _________.
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EASY

Under the isothermal condition, a gas at 300 K expands from 0.1 L to 0.25 L against a constant external pressure of 2 bar. The work done by the gas is

(Given that 1 L bar=100 J)

MEDIUM
For water at 100°C and 1 bar,
Δvap H-Δvap U=¯×102 J mol-1
(Round off to the Nearest Integer)
[Use : R=8.31 J mol-1 K-1
[Assume volume of H2O(l) is much smaller than volume of H2O(g). Assume H2O(g) treated as an ideal gas]
EASY
An ideal gas undergoes isothermal expansion at constant pressure. During the process:
EASY
When an ideal gas expands isothermally from 5 m3 to 10 m3 at 25°C against a constant pressure of 107 N·m-2, then the work done on the gas is
EASY
Three mole of an ideal gas expand isothermally and reversibly from 10 m3 to 20 m3 at 300 K, calculate the work done? R=8.314 J K-1 mol-1
HARD
One mole of an ideal gas at 900 K, undergoes two reversible processes, I followed by II, as shown below. If the work done by the gas in the two processes are same, the value of lnV3V2 is

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(U : internal energy, S: entropy, p: pressure, V: volume, R : gas constant) 

(Given: molar heat capacity at constant volume, CV,m of the gas is 52R)

Give your answer as the nearest integer.

HARD
The work done when 2 moles of an ideal gas expands reversibly and isothermally from a volume of 1 L to 10 L at 300 K is R=0.0083 kJ K mol-1
EASY

Two identical samples of gas are allowed to expand i isothermally and ii adiabatically. The amount of work done id then

EASY
The work done in ergs for the reversible expansion of one mole of an ideal gas from a volume of 10 litres to 20 litres at 25 °C is
MEDIUM

The three processes in a thermodynamic cycle shown in the figure are : Process 12 is isothermal; Process 23 is isochoric (volume remains constant); Process 13 is adiabatic.

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The total work done by the ideal gas in this cycle is,10 J. The internal energy decreases by, 20 J in the isochoric process. The work done by the gas in the adiabatic process is, -20 J. The heat added to the system in the isothermal process is

HARD
An ideal gas undergoes isothermal compression from 5 m3 to 1 m3 against a constant external pressure of 4 N m-2. The heat released in this process is 24 J mol-1K-1 and is used to increase the pressure of 1 mole of Al. The temperature of Al increases by: