EASY
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A sample of water is heated from 0 °C to 4 °C. Identify the correct relation between Cp and Cv (specific heats at constant pressure and constant volume respectively) for the process.

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Important Questions on Kinetic Theory

MEDIUM
An ideal gas follows a process described by PV2=C from P1,V1,T1 to P2,V2,T2 (C is a constant). Then
HARD

A long cylindrical pipe of radius 20 cm is closed at its upper end and has an airtight piston of negligible mass as shown. When a 50 kg mass is attached to the other end of piston, it moves down by a distance, Δl before coming to equilibrium. Assuming air to be an ideal gas, Δll (see figure) is close to g=10 m s-2, one atmospheric pressure is 105 Pa ),

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MEDIUM

An ideal gas undergoes a circular cycle centred at 4 atm, 4 L as shown in the diagram.

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The maximum temperature attained in this process is close to

MEDIUM
A vertical closed cylinder is separated into two parts by a frictionless piston of mass m and of negligible thickness. The piston is free to move along the length of the cylinder. The length of the cylinder above piston is l1, and that below the piston is l2, such that l1>l2. Each part of the cylinder contains n moles of an ideal gas at equal temperature T. If the piston is stationary, its mass m will be given by:
(R is universal gas constant and g is the acceleration due to gravity)
EASY
A cylinder closed at both ends is separated into two equal parts (45 cm each) by a piston impermeable to heat. Both the parts contain the same masses of gas at a temperature of 300 K and a pressure of 1 atm. If now the gas in one of the parts is heated such that the piston shifts by 5 cm, then the temperature and the pressure of the gas in this part after heating is 
EASY
Modern vacuum pumps can evacuate a vessel down to a pressure of 4.0 × 1 0 - 1 5  atm. at room temperature (300 K). Taking R = 8.3 JK-1  mole-1, 1 atm = 105 Pa and N Avogadro = 6 × 1 0 2 3 mole - 1 , the mean distance between molecules of gas in an evacuated vessel will be of the order of :
MEDIUM
The average distance between molecules of an ideal gas at STP is approximately of the order of
MEDIUM
Three moles of an ideal gas are in a rigid cubical box with sides of length 0.170m. The ratio of the forces that the gas exerts on each of the six sides of the box when the gas temperature are 27°C and 127°C is.
MEDIUM
An ideal gas filled in a cylinder occupies volume, V. The gas is compressed isothermally to the volume, V3. Now the cylinder valve is opened and the gas is allowed to leak keeping the temperature the same. What percentage of the number of molecules escape to bring the pressure in the cylinder back to its original value.
HARD
One mole of an ideal gas undergoes a linear process as shown in the figure below. Its temperature expressed as a function of volume, V is-
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HARD
An open glass tube is immersed in mercury in such a way that a length of 8 cm extends above the mercury level. The open end of the tube is then closed and sealed and the tube is raised vertically up by additional 46 cm. What will be length of the air column above mercury in the tube now ?
(Atmospheric pressure = 76 cm of Hg)
EASY
A given sample of an ideal gas occupies a volume, V at a pressure, P and absolute temperature, T. The mass of each molecule of the gas is m . Which of the following gives the density of the gas?
MEDIUM
One mole of an ideal gas passes through a process where pressure and volume obey the relation  P=Po1-12VoV2 . Here Po and Vo are constants. Calculate the change in the temperature of the gas if its volume changes from Vo  to  2Vo .
EASY
The state of an ideal gas was changed isobarically. The graph depicts three such isobaric lines. Which of the following is true about the pressures of the gas?
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MEDIUM
The equation of state for 2 g of oxygen at a pressure p and temperature T, when occupying a volume V will be
EASY
Two vessels separately contain two ideal gases A and B at the same temperature. The pressure of gas A is three times the pressure of gas B. Under these conditions, the density of gas A is found to be two times the density of B. The ratio of molecular weights of gas A and B i.e. MAMB is
EASY
A cylinder contains hydrogen gas at pressure of 249 kPa and temperature 27oC. Its density is: R=8.3 JK Mol1 K1
HARD
Two non-reactive monoatomic ideal gases have their atomic masses in the ratio 2 : 3. The ratio of their partial pressures, when enclosed in a vessel kept at a constant temperature, is 4 : 3. The ratio of their densities is 
EASY
 The temperature of an open room of volume 30 m3 increases from 17°C to 27°C due to the sunshine. The atmospheric pressure in the room remains 1×105 Pa. If ni and nf are the number of molecules in the room before and after heating, then nf-ni will be:
EASY
For the P-V diagram given for an ideal gas
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 Out of the following which one correctly represents the T-P diagram?