HARD
JEE Main
IMPORTANT
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A solution of a mixture of KCl and KOH was neutralized with 120 mL of 0.12 N HCl. After titration, the resultant solution was made acidic with HNO3. Then, excess of AgNO3 solution was added to precipitate the AgCl which weighed 3.7 g after drying. Calculate the percentage of KOH in the original mixture. (Give answer up to one decimal point)

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Important Questions on Volumetric Calculation

HARD
JEE Main
IMPORTANT
10.03 g of vinegar was diluted to 100 mL and a 25 mL sample was titrated with the 0.0176 M Ba(OH)2 solution. 34.30 mL was required for equivalence. What is the percentage of acetic acid in the vinegar?
MEDIUM
JEE Main
IMPORTANT

Zinc can be determined volumetrically by the precipitation reaction

3Zn2++24K+,Fe(CN)64+K2Zn3Fe(CN)62+6K+

A sample of zinc ore weighing 1.5432 g was prepared for a reaction and required 34.68 mL of 0.1043 M K4Fe(CN), for titration. What is the percentage of zinc in the ore?

HARD
JEE Main
IMPORTANT
5.5 g of a mixture of FeSO4.7H2O and Fe2SO43.9H2O requires 5.4 mL of 0.1 N KMnO4 solution for complete oxidation. Calculate the number of moles of hydrated ferric sulphate in the mixture.
MEDIUM
JEE Main
IMPORTANT

A chemist is preparing to analyse samples that will contain no more than 0.5 g of uranium. His procedure calls for preparing the uranium as U4+ ion and oxidising it by MnO4- in acid solution.

5U4++2MnO4-+6H2O5UO32++2Mn2++4H3O+

If he wants to react the total U4+ sample with a maximum of 50 mL of KMnO4 solution, concentration he choose is x × 10-2

Give the value of x to the nearest integer value.

MEDIUM
JEE Main
IMPORTANT
For the standardisation of a Ba(OH)2 solution, 0.2 g of potassium acid phthalate (weight of one mole=204.2 g) was weighed which was then titrated with Ba(OH)2 solution. The titration indicated equivalence at 27.80 mL of Ba(OH)2 solution. What is the molarity of the base? The equation for reaction is 2KHC8H4O4+ Ba(OH)22H2O+ 2K++ 2C8H4O42-+ Ba2+.
HARD
JEE Main
IMPORTANT
A sample of magnesium metal containing some magnesium oxide as an impurity was dissolved in 125 mL of 0.1 N H2SO4. The volume of hydrogen evolved at 27·3°C and 1 ATM was 120·1 mL. The resulting solution was found to be 0.02 N with respect to H2SO4. Calculate the percentage by weight of magnesium in the sample. Neglect any change in the volume of the solution.
HARD
JEE Main
IMPORTANT
A piece of aluminium weighing 2.7 g is treated with 75 mL of H2SO4 (specific gravity 1.18 containing 24.7% H2SO4 by weight). After the metal is completely dissolved, the solution is diluted to 400 mL. Calculate the molarity of free sulphuric acid in the resulting solution.
HARD
JEE Main
IMPORTANT
4.00 g of a mixture of NaCl and Na2CO3 was dissolved in water and the volume made up to 250 mL. 25 mL of this solution required 50 mL of N/10 HCl for complete neutralisation. Calculate the percentage composition of the original mixture.