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A tertiary butyl carbocation is more stable than a secondary butyl carbocation because of which of the following?

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Important Questions on Organic Chemistry- Some Basic Principles and Techniques

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The correct order of the basis strength of methyl substituted amines in aqueous solution is:
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Which of the following carbocations is expected to be the most stable?
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Which of the following is correct with respect to -I effect of the substituent? (R=alkyl group)
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The correct increasing order of the basic strength for the following compounds is:

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The most suitable method of separation of 1:1 mixture of ortho and para-nitrophenol is: