HARD
JEE Advanced
IMPORTANT
Earn 100

Addition of excess aqueous ammonia to a pink coloured aqueous solution of and gives an octahedral complex Y in the presence of air. In aqueous solution, complex Y behaves as 1 : 3 electrolyte. The reaction of X with excess HCl at room temperature results in the formation of a blue coloured complex Z. The calculated spin only magnetic moment of X and Z is 3.87 B.M., whereas it is zero for complex Y.
Among the following options, which statement(s) is(are) correct ?
(a)When X and Z are in equilibrium at 0°C, the colour of the solution is pink
(b)The hybridization of the central metal ion in Y is
(c)Z is a tetrahedral complex
(d)Addition of silver nitrate to Y gives only two equivalents of silver chloride

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Important Questions on Coordination Compounds
HARD
JEE Advanced
IMPORTANT
Among and , the total number of paramagnetic compounds is

HARD
JEE Advanced
IMPORTANT
Consider the following complex ions, P, Q and R.
The correct order of the complex ions, according to their spin-only magnetic moment values (in B.M.) is

HARD
JEE Advanced
IMPORTANT
The pair(s) of coordination complexes/ions exhibiting the same kind of isomerism is (are)
