HARD
JEE Advanced
IMPORTANT
Earn 100

Addition of excess aqueous ammonia to a pink coloured aqueous solution of MCl2.6H2O (X) and NH4Cl gives an octahedral complex Y in the presence of air. In aqueous solution, complex Y behaves as 1 : 3 electrolyte. The reaction of X with excess HCl at room temperature results in the formation of a blue coloured complex Z. The calculated spin only magnetic moment of X and Z is 3.87 B.M., whereas it is zero for complex Y.

Among the following options, which statement(s) is(are) correct ?

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Important Questions on Coordination Compounds

HARD
JEE Advanced
IMPORTANT
Among NiCO4, NiCl42-, CoNH34Cl2Cl, Na3CoF6, Na2O2 and CsO2, the total number of paramagnetic compounds is
HARD
JEE Advanced
IMPORTANT

Consider the following complex ions, P, Q and R.

P=FeF63-,Q=VH2O62+, R=FeH2O62+ 

The correct order of the complex ions, according to their spin-only magnetic moment values (in B.M.) is

HARD
JEE Advanced
IMPORTANT
The pair(s) of coordination complexes/ions exhibiting the same kind of isomerism is (are)