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Alkyl amines have alkyl groups as substituents on the nitrogen atom. Alkyl groups are releasing groups. Thus, they increase the electron density on the nitrogen atom and make the alkyl amine more basic than ammonia.

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Important Questions on Amines

MEDIUM

The major product formed in the reaction given below will be :

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MEDIUM
The amine which reacts with p-toluene sulphonyl chloride to give a clear solution which on acidification gives insoluble compound is
EASY
A mixture containing the following four compounds is extracted with 1 M HCl. The compound that goes to aqueous layer is:
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EASY
Describe a method for the identification of primary, secondary and tertiary amines. Also, write chemical equations of the reactions involved.
HARD

Aniline reacts with mixed acid (conc. HNO3 and conc. H2SO4 ) at 288 K to give P (51 %), Q (47%) and R (2%) . The major product(s) of the following reaction sequence is (are)

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MEDIUM
Among the following compounds, the increasing order of their basic strength is:

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EASY
The nitrosation of N,N-dimethylaniline takes place through the attack of electrophile:
HARD
The major product of the reaction is
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MEDIUM
The following reaction

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Is known by the name:
MEDIUM
A compound with molecular mass 180 is acylated with CH3COCl to get a compound with molecular mass 390. The number of amino groups presents per molecule of the former compound is
MEDIUM
Aniline reacts with excess Br2/H2O to give the major product
HARD

The major product obtained in the following reaction is:
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HARD
The compound  X C7H9N reacts with benzenesulfonyl chloride to give  Y C13H13NO2S which is insoluble in alkali. The compound X is
HARD
The product(s) of the following reaction sequence is(are)

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EASY

In the reaction sequence
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X and Y are, respectively,

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The test to distinguish primary, secondary and tertiary amines is:
HARD
The final product formed when methylamine is treated with NaNO 2 and HCl followed by hydrolysis is:
EASY
Which of the following compounds will form significant amount of meta product during mono-nitration reaction?
HARD

The major product of the following reaction is:

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MEDIUM

What will be the major product in the following mononitration reaction?

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