MEDIUM
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An ideal gas can't be liquefied because :

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Important Questions on States of Matter: Gases and Liquids

MEDIUM
When does a gas deviate the most from its ideal behavior?
MEDIUM
Given, van der Waal's constant for NH3, H2, O2 and CO2 are respectively 4.17, 0.244, 1.36 and 3.59. Which one of the following gases is most easily liquefied?
EASY
A gas such as carbon monoxide would be most likely to obey the ideal gas law at:
HARD
Which one of the following plots is correct for the behaviour of ideal and real gases?
EASY

Given below are two statement : one is labelled as Assertion A and the other is labelled as Reason R.
Assertion A:SO2( g) is adsorbed to a large extent than H2( g) on activated charcoal.

Reason R : SO2( g) has a higher critical temperature than H2( g)

In the light of the above statements, choose the most appropriate answer from the options given below.

MEDIUM

The variation of the compressibility factor (Z) with pressure (P in bar) for some gases, are shown in the figure below. Identify the gases (A),(B) and (C).

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MEDIUM
Which of the following two gases can be cooled from temperature by the Joule-Thomson effect?
HARD
Van der Waal's equation for a gas is stated as,

P=nRTV-nb-anV2.

This equation reduces to the perfect gas equation, P=nRTV When,
MEDIUM
Given the critical temperature and critical pressure of CO2 gas are 30°C and 72 atm respectively, find the approximate values of Van der Waals constants 'a' (in L2. atm. mol-2) and 'a' (in L. mol-1).
EASY

Among the following gases, the order of liquefiability is
a) SO2
b) CO2
c) CH4
d) NH3

MEDIUM
The pressure p and volume V isotherm of a van der Waals' gas, at the temperature at which it undergoes gas to liquid transition, is correctly represented by
EASY
According to Andrews isothermal at what temperature the carbon dioxide gas starts to condense at 73 atmosphere?
EASY

The number of statement's, which are correct with respect to the compression of carbon dioxide from point (a) in the Andrews isotherm from the following is _________.

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A. Carbon dioxide remains as a gas upto point (b)
B. Liquid carbon dioxide appears at point (c)
C. Liquid and gaseous carbon dioxide coexist between points (b) and (c)
D. As the volume decreases from (b) to (c), the amount of liquid decreases 

EASY
In the following compressibility factor (Z) vs pressure graph at 300 K, the compressibility of CH4 at pressure < 200 bar deviates from ideal behavior because

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HARD
One mole of a monoatomic real gas satisfied the equation pV-b=RT where b is a constant. The relationship of interatomic potential V(r) and interatomic distance r for the gas is given by
HARD
If Z is the compressibility factor, then Van der Waal's equation at low pressure can be written as:
EASY

Which of the following gases can be absorbed in more proportion?

MEDIUM
The critical temperatures of four gases K,L,M and N are 154.3 K,5.3 K,33.2 K and 126 K respectively. Which of these gases will liquify first if they start cooling from 500 K to their critical temperatures?
MEDIUM
Consider the van der Waal's constants, a and b, for the following gases.
Gas Ar Ne Kr Xe
a/(atm dm6 mol-2) 1.3 0.2 5.1 4.1
b/(10-2 dm3 mol-1) 3.2 1.7 1.0 5.0

Which gas is expected to have the highest critical temperature?