Write labelled chemical equations to show what happens when vapours of butan-2-ol are passed over heated copper at 573 K

When secondary alcohols are passed through heated copper at high temperature, they undergo oxidation and ketones are formed. In the same way, butan-2-ol reacts with heated copper to form acetone. The equation for the reaction is: CH 3 - CH 2 - CH OH - CH 3 → dehydrogenation Cu , 573 K CH 3 COCH 3

Write the chemical equation for the following conversion : Anisole to 4-Nitroanisole

Anisole reacts with the nitrating mixture to give 2 - nitroanisole and 4 - nitroanisole because, alkoxy group is EDG (electron donating group) and electron density increase at ortho and para position of benzene substituents ring.

Write chemical equations for the following conversions : Phenol to Benzene

When phenol is distilled with Zn dust, the - OH group is replaced by a hydrogen atom. Zinc removes the oxygen of the phenolic group as zinc oxide, to yield the parent hydrocarbon. The reaction can be given as follows : C 6 H 5 OH + Zn → C 6 H 6 + ZnO Phenol Zinc dust Benzene This reaction is an example of deoxygenation of phenol.

Arrange the following alcohols in the decreasing order of their boiling points: Pentan-1-ol, 2-methyl-butan-2-ol, 3-methyl butan-2-ol.

Given compounds are: CH 3 CH 2 C CH 3 OH CH 3 - 2-methyl butan-2-ol is a teritiary alcohol, CH 3 CH 2 CH 2 CH 2 CH 2 OH - pentan-1-ol is a primary alcohol and CH 3 CH CH 3 CH OH CH 3 - 3-methyl butan-2-ol is a secondary alcohol. Boiling point of alcohols is determined by the ease and extent of H-bonding among the alcohol molecules. Tertiary alcohols being highly hindered will have the least hydrogen bonding and thus low boiling point as compared to less hindered secondary alcohol. Therefore, the decreasing order of boiling points of alcohol compounds are: Pentan - 1 - ol > 3 - methyl butan - 2 - ol > 2 - methyl butan - 2 - ol .

E M B I B E

EMBIBE CHAPTER WISE PREVIOUS YEAR PAPERS FOR CHEMISTRY>Chapter -1 - Alcohols, Phenols and Ethers>Goa Board-2018>Q 2

MEDIUM

12th Goa Board

IMPORTANT

Earn 100

An organic compound $' A'$ with molecular formula $C_{7} H_{8} O$ reacts with $HI$ and forms compound $' B'$ . Compound $' B'$ on heating with zinc dust gets converted to the simplest aromatic hydrocarbon. Write equations for the above reactions and name the compounds $' A'$ and $' B'$ .

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