MEDIUM
JEE Main/Advance
IMPORTANT
Earn 100

At 380 °C, the half-life period for the first order decomposition of H2O2 is 360 min. The energy of activation of the reaction is 200 kJ mol-1. Calculate the time required for 75% decomposition at 450 °C.

50% studentsanswered this correctly

Important Questions on Chemical Kinetics

MEDIUM
JEE Main/Advance
IMPORTANT
A first order reaction AB, requires activation energy of 70 kJ mol-1. When a 20% solution of A was kept at 25 °C for 20 minutes, 25% decomposition took place. What will be the percent decomposition in the same time in a 30% solution maintained at 40 °C? Assume that activation energy remains constant in this range of temperature.
MEDIUM
JEE Main/Advance
IMPORTANT

For the elementary reaction 2 A+B22AB. Calculate how much the rate of reaction will change if the volume of the vessel is reduced to one third of its original volume?

MEDIUM
JEE Main/Advance
IMPORTANT

A first order reaction 75% Completed in 72 min. How long time will it take for 87.5% completion

EASY
JEE Main/Advance
IMPORTANT

A first order reaction has a rate constant 1.5×10-3sec-1. How long will 5.0 g of this reactant take to reduce to1.25 g.

Report your answer in the nearest integer value.

MEDIUM
JEE Main/Advance
IMPORTANT

A drug is known to be ineffective after it has decomposed 30%. The original concentration of a sample was 500 units / mL. when analyzed 20 months later, the concentration was found to be 420 units/mL . Assuming that decomposition is of I order, what will be the expiry time of the drug?

MEDIUM
JEE Main/Advance
IMPORTANT

At 100°C the gas reaction A2 B+C was observed to be of first order. On starting with pure A it is found that at the end of 10 minutes the total pressure of system is 176 mm.Hg and after a long time 270 mmHg. From these data find initial pressure of A.

MEDIUM
JEE Main/Advance
IMPORTANT

The following data were obtained in experiment on inversion of cane sugar.

Time (minutes) 0 60 120 180 360
Angle of rotation (degree) +13.1 +11.6 +10.2 +9.0 +5.87 -3.8

Show that the reaction is of first order. After what time would you expect a zero reading in polarimeter?

MEDIUM
JEE Main/Advance
IMPORTANT

Decomposition of reaction 3 Ag2 Bg+2Cg follows first order kinetics. Starting with pure 'A' pressure developed after 20 min and infinite time are 3.5 and 4 atm respectively.

What is time taken for 75% decomposition of A?