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Barium chloride salt solution used for testing sulphate radical. 

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Important Questions on Inorganic Qualitative Analysis

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Sodium nitroprusside, when added to an alkaline solution of sulphide ions, produce a
MEDIUM
HgCl2 and I2 both when dissolved in water containing I- ions the pair of species formed is:
EASY
Reaction of an inorganic sulphite X with dilute H2SO4 generated compound Y. Reaction of Y with NaOH gives X. Further, the reaction of X with Y and water affords compound Z, Y and X, respectively, are :
EASY

The blue colour produced when a starch solution is added to a solution containing traces of I2 and KI is due to

(I) formation of I3-

(II) formation of an inclusion complex

(III) Oxidation of starch

(IV) Oxidation of I2

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A chloride salt solution acidified with dil. HNO3  gives a curdy white precipitate, [A], on addition of AgNO3. [A] on treatment with NH4OH gives a clear solution, B.
HARD
When a mixture of NaCl,K2Cr2O7 and concentrated H2SO4 is heated in a dry test tube, a red vapour X is evolved. This vapour X turns an aqueous solution of NaOH yellow due to the formation of Y. X and Y, respectively, are:
EASY
On heating, lead (ll) nitrate gives a brown gas (A). The gas (A) on cooling changes to a colourless solid/liquid (B). (B) on heating with NO changes to ablue solid (C). The oxidation number of nitrogen in solid (C) is:
EASY
In the detection of II group acid radical, the salt containing chloride is treated with concentrated sulphuric acid, the colourless gas is liberated. The name of the gas is
MEDIUM
When a solution of mixture having two inorganic salts was treated with freshly prepared ferrous sulphate in acidic medium, a dark brown ring was formed whereas on treatment with neutral FeCl3, it gave deep red colour which disappeared on boiling and a brown red ppt was formed. The mixture contains
HARD
The reagent(s) that can selectively precipitate S2- from a mixture of S2- and SO42- in aqueous solution is (are)
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A white sodium salt dissolves readily in water to give a solution which is neutral to litmus. When silver nitrate solution is added to the before mentioned solution, a white precipitate is obtained which does not dissolve in dilute nitric acid. The anion is:
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Which combines with Fe2+ to form brown complex?
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Consider the following reactions:
NaCl+K2Cr2O7+H2SO4Conc.A+ side products
A+NaOHB+ side products
B+H2SO4dilute+H2O2C+ side products
The sum of the total number of atoms in one molecule each of A,B and C is ________
MEDIUM
The sodium salt of an organic acid X produces effervescence with concentrated H2SO4. X reacts with the acidified aqueous CaCl2 solution to give a white precipitate which decolourises acidic solution of KMnO4. X is
HARD

Distinguish between the following pair of compounds using a reagent as a chemical test:

  • Magnesium chloride and magnesium nitrate solution.
EASY
When treated with conc. HCl, MnO2 yields gas (X) which further reacts with Ca(OH)2 to generate a white solid (Y) reacts with dil. HCl to produce the same gas X. the solid Y is
EASY

A sample of potassium salt was contaminated with potassium chloride. The tests were carried out on the contaminated sample.

TEST: An equal volume of barium nitrate solution is added to a solution of the solid. A precipitate forms. What colour will the precipitate be?

MEDIUM
Name the anion present in compound B: When barium chloride solution is added to a solution of compound B, a white precipitate, insoluble in dilute hydrochloric acid, is obtained.
EASY

A sample of potassium salt was contaminated with potassium chloride. The tests were carried out on the contaminated sample.

TEST: An equal volume of barium nitrate solution is added to a solution of the solid. A precipitate forms which will disappear if dilute nitric acid is added. Why?

MEDIUM

A sample of potassium salt was contaminated with potassium chloride. The tests were carried out on the contaminated sample.

TEST: An equal volume of barium nitrate solution is added to a solution of the solid. A precipitate forms. Name the precipitate and explain why it forms?