MEDIUM
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Benzaldehyde on reaction with N, N – dimethyl aniline in the presence of strong acid forms

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Important Questions on Carbonyl Compounds and Carboxylic Acids

HARD
In the following reaction sequence, the amount of D (in g) formed from 10 moles of acetophenone is ____.

(Atomic weights in mol-1: H=1,C=12,N=14,O=16,Br=80.  The yield (%) corresponding to the product in each step is given in the parenthesis)

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HARD
Columns 1, 2 and 3 contain starting materials, reaction conditions and type of reactions respectively.
 
Column 1 Column 2 Column 3
(I) Toulene (i) NaOH/Br2 (P) Condensation
(II) Acetophenone (ii) Br2/hv (Q) Carboxylation
(III) Benzaldehyde (iii) CH3CO2O/CH3COOK (R) Substitution
(IV) Phenol (iv) NaOH/CO2 (S) Haloform
For the synthesis of benzoic acid the only correct combination is
HARD

After completion of the reactions (I and II), the organic compound(s) in the reaction mixtures is(are):

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HARD
The test performed on compound x and their inferences are:
 
Test Inference
a 2, 4 - DNP test Coloured precipitate yellow
b Iodoform test Yellow precipitate
c Azo-dye test No dye formation

Compound x is:

EASY

Which is the most suitable reagent for the following conversion?

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MEDIUM
Reaction of benzaldehyde with acetic anhydride in the presence of base is known as _____ and the product 
EASY

Mention the reagents used for the following conversions:

(m) C6H5CH3AC6H5CHO

(n) CH3CHOBCH3COOC2H5

(o) C6H5CHOCC6H5COCHOHC6H5

(p) CH3COCH3DCH32COHCH2COCH3

(q) CH3CH2COOHECH3CHBrCOOH

(r) CH3COCH3FCH3COCH2Br

MEDIUM
Which is the main organic product obtained by the reaction of 2, 2, 2 trichloro ethanal with calcium hydroxide?
MEDIUM
In the following reaction
carbonyl compound +MeOHHClacetal

Rate of the reaction is the highest for:
EASY
Reaction of a carbonyl compound with one of the following reagents involves nucleophilic addition followed by elimination of water. The reagent is:
MEDIUM
Which of the following reagents would distinguish cis-cyclopenta-1, 2-diol from the trans-isomer?
EASY
Write chemical equations to illustrate the following name reactions: Benzoin condensation.