The CORRECT statement for CH 3 - X ( X = F , Cl , Br , l ) is

CH 3 - F has highest CH 3 - X bond enthalpy and lowest dipole moment

CH 3 l has lowest CH 3 - X bond enthalpy and lowest dipole moment

CH 3 - Br has highest CH 3 - X bond enthalpy and highest dipole moment

CH 3 - Cl has highest CH 3 - X bond enthalpy and CH 3 - Br has highest dipole moment

For the compounds CH 3 Cl, CH 3 Br, CH 3 I and CH 3 F, the correct order of increasing C-halogen bond length is :

CH 3 F < CH 3 Cl < CH 3 Br < CH 3 I

CH 3 F < CH 3 Br < CH 3 Cl < CH 3 I

CH 3 F < CH 3 I < CH 3 Br < CH 3 Cl

CH 3 Cl < CH 3 Br < CH 3 F < CH 3 I

EASY

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${CF}_{4}$ is a gas, ${CCl}_{4}$ is a liquid, ${CBr}_{4}$ and ${Cl}_{4}$ are solids at room temperature. The highest bond enthalpy is observed in ______

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Important Questions on Haloalkanes and Haloarenes(OoS)

HARD

Chemistry>Organic Chemistry>Haloalkanes and Haloarenes(OoS)>Nature of C - X Bond in Haloalkanes

Which of the following is the most correct electron displacement for a nucleophile reaction to take place?

MEDIUM

Chemistry>Organic Chemistry>Haloalkanes and Haloarenes(OoS)>Nature of C - X Bond in Haloalkanes

The most polar compound among the following is:

EASY

Chemistry>Organic Chemistry>Haloalkanes and Haloarenes(OoS)>Nature of C - X Bond in Haloalkanes

Consider the reaction

{CH}_{3} {CH}_{2} {CH}_{2} Br + NaCN \to {CH}_{3} {CH}_{2} {CH}_{2} CN + NaBr

This reaction will be the fastest in

EASY

Chemistry>Organic Chemistry>Haloalkanes and Haloarenes(OoS)>Nature of C - X Bond in Haloalkanes

The correct pair(s) of the ambident nucleophiles is (are):
(A)

AgCN / KCN

(B)

RCOOAg / RCOOK

(C)

{AgNO}_{2} / {KNO}_{2}

(D)

AgI / KI

MEDIUM

Chemistry>Organic Chemistry>Haloalkanes and Haloarenes(OoS)>Nature of C - X Bond in Haloalkanes

Which of the following has the highest dipole moment?

MEDIUM

Chemistry>Organic Chemistry>Haloalkanes and Haloarenes(OoS)>Nature of C - X Bond in Haloalkanes

The compound

A

on reaction with chlorine in presence of

u . v .

light gives

B

; which when reacted with

{AgNO}_{2}

in the solvent

N, N

-dimethylformamide, gives

2

-Nitrobutane. The compound

A

EASY

Chemistry>Organic Chemistry>Haloalkanes and Haloarenes(OoS)>Nature of C - X Bond in Haloalkanes

For a given alkyl group, the reactivity order of halides in

{SN}_{1}

reaction is

MEDIUM

Chemistry>Organic Chemistry>Haloalkanes and Haloarenes(OoS)>Nature of C - X Bond in Haloalkanes

The compound having longest

C - Cl

bond is:

MEDIUM

Chemistry>Organic Chemistry>Haloalkanes and Haloarenes(OoS)>Nature of C - X Bond in Haloalkanes

The CORRECT statement for

{CH}_{3} - X (X = F, Cl, Br, l)

HARD

Chemistry>Organic Chemistry>Haloalkanes and Haloarenes(OoS)>Nature of C - X Bond in Haloalkanes

The dipole moment of chlorobenzene is lower than that of cyclohexyl chloride. Explain.

HARD

Chemistry>Organic Chemistry>Haloalkanes and Haloarenes(OoS)>Nature of C - X Bond in Haloalkanes

Explain why alkyl halides, though polar, are immiscible with water?

EASY

Chemistry>Organic Chemistry>Haloalkanes and Haloarenes(OoS)>Nature of C - X Bond in Haloalkanes

Which of the following statements is true in the case of alkyl halides?

MEDIUM

Chemistry>Organic Chemistry>Haloalkanes and Haloarenes(OoS)>Nature of C - X Bond in Haloalkanes

Which of the following will most readily give the dehydrohalogenation product?

MEDIUM

Chemistry>Organic Chemistry>Haloalkanes and Haloarenes(OoS)>Nature of C - X Bond in Haloalkanes

The major product of the following reaction is:
Question Image

EASY

Chemistry>Organic Chemistry>Haloalkanes and Haloarenes(OoS)>Nature of C - X Bond in Haloalkanes

How do the bond lengths of

C - X

bonds (

X = F, Cl, Br, I

) in haloalkanes vary and why?

EASY

Chemistry>Organic Chemistry>Haloalkanes and Haloarenes(OoS)>Nature of C - X Bond in Haloalkanes

The correct sequence of bond enthalpy of ' $\mathrm{C}-\mathrm{X}$ bond is:

EASY

Chemistry>Organic Chemistry>Haloalkanes and Haloarenes(OoS)>Nature of C - X Bond in Haloalkanes

For the compounds CH₃Cl, CH₃Br, CH₃I and CH₃F, the correct order of increasing C-halogen bond length is :

MEDIUM

Chemistry>Organic Chemistry>Haloalkanes and Haloarenes(OoS)>Nature of C - X Bond in Haloalkanes

The order of reactivities of the following alkyl halides for an

S_{N} 2

reaction is

MEDIUM

Chemistry>Organic Chemistry>Haloalkanes and Haloarenes(OoS)>Nature of C - X Bond in Haloalkanes

Of the following compounds which will have a zero dipole moment ?

EASY

Chemistry>Organic Chemistry>Haloalkanes and Haloarenes(OoS)>Nature of C - X Bond in Haloalkanes

In the nucleophilic substitution reactions

(S_{N} 2 or S_{N} 1)

the reactivity of alkyl halides follows the sequence

CF4 is a gas, CCl4 is a liquid, CBr4 and Cl4 are solids at room temperature. The highest bond enthalpy is observed in ______

Important Questions on Haloalkanes and Haloarenes(OoS)

Learn and Prepare for any exam you want !

${CF}_{4}$ is a gas, ${CCl}_{4}$ is a liquid, ${CBr}_{4}$ and ${Cl}_{4}$ are solids at room temperature. The highest bond enthalpy is observed in ______