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IMPORTANT
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Calculate the work in kJ of an isobaric reversible expansion of three moles of an ideal gas while it is heated from 298 K to 400 K.

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Important Questions on Thermodynamics

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JEE Main
IMPORTANT

Calculate the work in kJ of an isothermal reversible expansion of three moles of water vapour from 5.0×104 to 2.0×104 Pa at 330 K.

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JEE Main
IMPORTANT

The heat of combustion of graphite at 298 K is -393.795 kJ/mol, while that of diamond's combustion at the same temperature is -395.692 kJ/mol. The specific heats for these substances are 720.83 and 505.58 J kg-1 K-1, respectively. Calculate the heat of graphite's transformation into diamond in kJ/mol at 298 K.

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JEE Main
IMPORTANT
A cylinder of cooking gas in a household contains 11.6 kg of butane. The thermochemical reaction for the combustion of butane is 2C4H10g+13O2g8CO2g+10H2Ol; ΔH=-2658 KJ/mol. If the household needs 15000 KJ of energy per day, the cooking gas cylinder will last for about:
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JEE Main
IMPORTANT
For the reaction AB, ΔH°=7.5 kJ mol-1 and ΔS°=25 J mol-1, the value of ΔG° and the temperature, at which the reaction reaches equilibrium are, respectively. 
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JEE Main
IMPORTANT

Diborane is formed from the elements as shown in equation 1.

Given that,  2Bs+3H2gB2H6g    ...1

H2OlH2Og  ΔH10=44 kJ

2B+3/2O2gB2O3s  ΔH20=-1273 kJ

B2H6g+3O2gB2O3s+3H2Og  ΔH30=-2035 kJ

H2g+1/2O2gH2Ol  ΔH40=286 kJ

the ΔH0 for the reaction (1) is:

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JEE Main
IMPORTANT
The ΔH for vaporisation of a liquid is 20 kJ/mol. Assuming ideal behaviour, the change in internal energy for the vaporization of 1 mole of the liquid at 60 °C and 1 bar is close to:
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JEE Main
IMPORTANT
Given that the bond energies of: NN is 946 kJ mol-1, H-H is 435 kJ mol-1, N-N is 159 kJ mol-1, and N-H is 389 kJ mol-1, the heat of formation of hydrazine in the gas phase in kJ mol-1 is:
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JEE Main
IMPORTANT
For the reaction N2+3X22NX3 where X=F, Cl (the average bond energies are F-F=155 kJ mol-1, N-F=272 kJ mol-1, Cl-Cl=242 kJ mol-1, N-Cl=200 kJ mol-1 and NN=941 kJ mol-1). The heats of the formation of NF3 and NCl3 in kJ mol-1, respectively, are closest to: