Carbonic acid, ${\mathrm{H}}_2{\mathrm{CO}}_3$, is a diprotic acid for which ${\mathrm{K}}_{{\mathrm{a}}_1}=4.2\times {10}^{-7}$, and ${\mathrm{K}}_{{\mathrm{a}}_2}=4.7\times {10}^{-11}$. The solution which will have a $\mathrm{pH}$ closest to $9$ is-