
Comprehension:
What is the compound A from the following observations?
Some observations related to an unknown inorganic substance A are presented below.
A has a molecular weight of 267, and it is a yellowish-white deliquescent solid, and it sublimes on heating.
A reacts violently with water, forming solution B.
When a solution of and is added to solution B, a white gelatinous precipitate is obtained.
A sample of B also gives a curdy white precipitate C on addition of dilute nitric acid and silver nitrate solution. This white precipitate C readily dissolves when dilute is added, though a gelatinous white precipitate D is formed in its place with excess
Precipitate D is filtered off and is dissolved in excess to give a clear solution E.
When is passed through solution E, compound D is re-precipitated.
Substance A unchanged in dry ether, when this solution is reacted with excess it transforms to G.
What is the compound A from the following observations?
A has a molecular weight of 267, and it is a yellowish-white deliquescent solid, and it sublimes on heating.
A sample of B also gives a curdy white precipitate C on addition of dilute nitric acid and silver nitrate solution. This white precipitate C readily dissolves when dilute is added, though a gelatinous white precipitate D is formed in its place with excess
Precipitate D is filtered off and is dissolved in excess to give a clear solution E.
When is passed through solution E, compound D is re-precipitated.
Substance A unchanged in dry ether, when this solution is reacted with excess it transforms to G.

Important Questions on The p-Block Elements





I. It is prepared by the oxidation of sodium borohydride with iodine.
II. It undergoes cleavage reactions with Lewis bases to give borane adducts.
III. It is produced on an industrial scale by the reaction of with .
IV. It is readily hydrolysed by water to give borazine.
V. It burns in oxygen and gives boron trioxide.













