In an experiment, m grams of a compound X (gas/liquid/solid) taken in a container is loaded in a balance as shown in figure I below. In the presence of a magnetic field, the pan with X is either deflected upwards (figure II ), or deflected downwards (figure III ), depending on the compound X . Identify the correct statement(s).

If X is O 2 ( g ) , deflection of the pan is downwards.

If X is C 6 H 6 ( l ) , deflection of the pan is downwards

The ground state energy of hydrogen atom is - 13.6 e V . Consider an electronic state Ψ of H e + whose energy, azimuthal quantum number and magnetic quantum number are - 3.4 e V , 2 and 0 respectively. Which of the following statement(s) is(are) true for the state Ψ ?

The nuclear charge experienced by the electron in this state is less than 2 e , where e is the magnitude of the electronic charge.

MEDIUM

JEE Advanced

IMPORTANT

Earn 100

Consider the Bohr's model of a one-electron atom where the electron moves around the nucleus. In the following List-I contains some quantities for the $n^{t h}$ orbit of the atom and List-II contains options showing how they depend on $n$ .

List - I List - II

(I) Radius of the $n^{t h}$ orbit $(P)$ $\propto n^{- 2}$

(II) Angular momentum of the electron in the $n^{t h}$ orbit $(Q)$ $\propto n^{- 1}$

(III) Kinetic energy of the electron in the $n^{t h}$ orbit $(R)$ $\propto n^{0}$

(IV) Potential energy of the electron in the $n^{t h}$ orbit $(S)$ $\propto n^{1}$

$(T)$ $\propto n^{2}$

$(U)$ $\propto n^{1 / 2}$

Which of the following options has the correct combination considering List-I and List-II?

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Important Questions on Structure of Atom

HARD

JEE Advanced

IMPORTANT

EMBIBE CHAPTER WISE PREVIOUS YEAR PAPERS FOR CHEMISTRY>Chapter 2 - Structure of Atom>JEE Advanced Paper 2 - 2019>Q 6

Consider the Bohr's model of a one-electron atom where the electron moves around the nucleus. In the following List-I contains some quantities for the

n^{t h}

orbit of the atom and List-II contains options showing how they depend on

n

List - I	List - II
(I) Radius of the $n^{t h}$ orbit	$(P)$ $\propto n^{- 2}$
(II) Angular momentum of the electron in the $n^{t h}$ orbit	$(Q)$ $\propto n^{- 1}$
(III) Kinetic energy of the electron in the $n^{t h}$ orbit	$(R)$ $\propto n^{0}$
(IV) Potential energy of the electron in the $n^{t h}$ orbit	$(S)$ $\propto n^{1}$
	$(T)$ $\propto n^{2}$
	$(U)$ $\propto n^{1 / 2}$

Which of the following options has the correct combination considering List-I and List-II?

HARD

JEE Advanced

IMPORTANT

EMBIBE CHAPTER WISE PREVIOUS YEAR PAPERS FOR CHEMISTRY>Chapter 2 - Structure of Atom>JEE Advanced Paper 1 - 2018>Q 7

Among the species given below, the total number of diamagnetic species is ___.

H a t o m, N O_{2} m o n o m e r, O_{2}^{-}

(superoxide), dimeric sulphur in vapour phase,

{Mn}_{3} O_{4}, {({NH}_{4})}_{2} [{FeCl}_{4}], {({NH}_{4})}_{2} [{NiCl}_{4}], K_{2} {MnO}_{4}, K_{2} {CrO}_{4}

HARD

JEE Advanced

IMPORTANT

EMBIBE CHAPTER WISE PREVIOUS YEAR PAPERS FOR CHEMISTRY>Chapter 2 - Structure of Atom>JEE Advanced Paper 1 - 2017>Q 8

The wave function,

ψ_{n, l, m_{l}}

is a mathematical function whose value depends upon spherical polar coordinates

(r, θ, ϕ)

of the electron and characterized by the quantum numbers

n, l

and

m_{l}

. Here

r

is distance from nucleus,

θ

is colatitude and

ϕ

is azimuth. In the mathematical functions given in the Table, Z is atomic number and

a_{o}

is Bohr radius.

Column – 1	Column – 2	Column – 3
(I) $1 s$ orbital	(i) $ψ_{n, l, m_{l}} \propto {(\frac{Z}{a_{o}})}^{\frac{3}{2}} e^{- (\frac{Zr}{e_{o}})}$	(P)
(II) $2 s$ orbital	(ii) One radial node	(Q) Probability density at nucleus $\propto \frac{1}{a_{o}^{3}}$
(III) $2 p_{z}$ orbital	(iii) $ψ_{n, l, m_{l}} \propto {(\frac{Z}{a_{o}})}^{\frac{5}{2}} {re}^{- (\frac{Zr}{2 a_{o}})} \cos θ$	(R) Probability density is maximum at nucleus
(IV) $3 d_{z}^{2}$ orbital	(iv) $x y$ -plane is a nodal plane	(S) Energy needed to excite an electron from $n = 2$ state to $n = 4$ state is $\frac{27}{32}$ times the energy needed to excite electron from $n = 2$ state to $n = 6$ state.

For hydrogen atom, what is the only CORRECT combination?

HARD

JEE Advanced

IMPORTANT

EMBIBE CHAPTER WISE PREVIOUS YEAR PAPERS FOR CHEMISTRY>Chapter 2 - Structure of Atom>JEE Advanced Paper 1 - 2017>Q 9

The wave function,

ψ_{n, l, m_{l}}

is a mathematical function whose value depends upon spherical polar coordinates

(r, θ, ϕ)

of the electron and characterized by the quantum numbers

n, l

and

m_{l}

. Here

r

is the distance from the nucleus,

θ

is colatitude and

ϕ

is azimuth. In the mathematical functions given in the Table,

Z

is the atomic number and

a_{o}

is Bohr radius

Column 1	Column 2	Column 3
(I) $1 s$ orbital	(i) $ψ_{n, l, m_{l}} \propto {(\frac{Z}{a_{o}})}^{\frac{3}{2}} e^{- (\frac{Zr}{e_{o}})}$	(P)
(II) $2 s$ orbital	(ii) One radial node	(Q) Probability density at the nucleus $\propto \frac{1}{a_{o}^{3}}$ .
(III) $2 p_{z}$ orbital	(iii) $ψ_{n, l, m_{l}} \propto {(\frac{Z}{a_{o}})}^{\frac{5}{2}} {re}^{- (\frac{Zr}{2 a_{o}})} \cos θ$	(R) Probability density is maximum at the nucleus.
(IV) $3 d_{z}^{2}$ orbital	(iv) $xy$ -plane is a nodal plane	(S) Energy needed to excite an electron from $n = 2$ state to $n = 4$ state is $\frac{27}{32}$ times the energy needed to excite are electron from $n = 2$ state to $n = 6$ state.

For

{He}^{+}

ion, the only incorrect combination

HARD

JEE Advanced

IMPORTANT

EMBIBE CHAPTER WISE PREVIOUS YEAR PAPERS FOR CHEMISTRY>Chapter 2 - Structure of Atom>JEE Advanced Paper 1 - 2017>Q 10

The wave function,

ψ_{n, l, m_{l}}

is a mathematical function whose value depends upon spherical polar coordinates

(r, θ, ϕ)

of the electron and characterized by the quantum numbers

n, l

and

m_{l}

. Here

r

is the distance from the nucleus,

θ

is colatitude and

ϕ

is azimuth. In the mathematical functions given in the Table,

Z

is the atomic number and

a_{o}

is Bohr radius

Column 1	Column 2	Column 3
(I) $1 s$ orbital	(i) $ψ_{n, l, m_{l}} \propto {(\frac{Z}{a_{o}})}^{\frac{3}{2}} e^{- (\frac{Zr}{e_{o}})}$	(P)
(II) $2 s$ orbital	(ii) One radial node	(Q) Probability density at the nucleus $\propto \frac{1}{a_{o}^{3}}$ .
(III) $2 p_{z}$ orbital	(iii) $ψ_{n, l, m_{l}} \propto {(\frac{Z}{a_{o}})}^{\frac{5}{2}} {re}^{- (\frac{Zr}{2 a_{o}})} \cos θ$	(R) Probability density is maximum at the nucleus.
(IV) $3 d_{z}^{2}$ orbital	(iv) $xy$ -plane is a nodal plane	(S) Energy needed to excite an electron from $n = 2$ state to $n = 4$ state is $\frac{27}{32}$ times the energy needed to excite are electron from $n = 2$ state to $n = 6$ state.

For the given orbital in column 1, the only correct combination for any hydrogen-like species is

MEDIUM

JEE Advanced

IMPORTANT

EMBIBE CHAPTER WISE PREVIOUS YEAR PAPERS FOR CHEMISTRY>Chapter 2 - Structure of Atom>JEE Advanced Paper 1 - 2016>Q 11

P

is the probability of finding the

1 s

electron of the hydrogen atom in a spherical shell of infinitesimal thickness,

dr

, at a distance,

r

, from the nucleus. The volume of this shell is

4 π r^{2} d r

. The qualitative sketch of the dependence of

P

r

is:

Important Questions on Structure of Atom

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