EASY
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Enantiomers have the same physical properties.
 
 

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Important Questions on Organic Chemistry- Some Basic Principles and Techniques

HARD

For the given compound X, the total number of optically active stereoisomers is ____.

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MEDIUM
Among the following, the conformation that corresponds to the most stable conformation of meso-butane-2,3-diol is
HARD
The total number of optically active alkynes having molecular formula C3FCBrI is
MEDIUM

Represent the union of two sets by Venn diagram for each of the following.

X={x | x is a prime number between 80 and 100}

Y={y | y is an odd number between 90 and 100}

MEDIUM
According to Cahn-Ingold-Prelog sequence rules, the correct order of priority for the given groups is 
MEDIUM

(+) - mandelic acid has a specific rotation of 158o. What would be the observed specific rotation of a mixture of 25% (-) - mandelic acid and 75% (+) - mandelic acid ?

MEDIUM
Which of the following molecules are chiral ?

I. Trans-1-chloro-2-methylcyclopropane

II. Cis-1-chloro-2-methylcyclopropane

III. 1-chloro-1-methylcyclopropane

​IV. Cis-1, 2-dichlorocyclopropane
EASY
What observed rotation is expected if a 1.5 M solution of (R)-2-butanol is mixed with an equal volume of a 0.75 M solution of racemic 2-butanol and the resulting solution is analyzed in a sample container that is 1 dm long ? The specific rotation of (R)-2-butanol as -13.9mL g-1dm-1.
MEDIUM
Dextrorotatory α-pinene has a specific rotation α D 2 0 = +  51.3 . A sample of α-pinene containing both the enantiomers was found to have a specific rotation value α D 2 0 = +  30.8 . The percentages of the (+) and (-) enantiomers present in the sample are, respectively.
HARD

Trans-3,6-Dimethyl oct-4-ene (A) exists in two diastereomers  I and II .
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Which statements is true about I and II ?