EASY

Earn 100

Express the relation among the conductivity of a solution in the cell, the cell constant and the resistance of the solution in the cell?

Important Questions on Electrochemistry

MEDIUM

Chemistry>Physical Chemistry>Electrochemistry>Conductance in Electrolytic Solutions

The electrical resistance of a column of

0.05 MNaOH

solution of diameter

1 cm

and length

50 cm

6.5 \times 10^{3} ohm .

Its molar conductivity will be

EASY

Chemistry>Physical Chemistry>Electrochemistry>Conductance in Electrolytic Solutions

The value of electrical resistance at super conductivity state is

EASY

Chemistry>Physical Chemistry>Electrochemistry>Conductance in Electrolytic Solutions

If the conductivity of mercury at

0 ° C

1.07 \times 10^{6} S m^{- 1}

and the resistance of a cell containing mercury is

0.243 Ω,

then the cell constant of the cell is

x \times 10^{4} m^{- 1} .

The value of

x

is ______ . (Nearest integer)

MEDIUM

Chemistry>Physical Chemistry>Electrochemistry>Conductance in Electrolytic Solutions

The resistance of a conductivity cell containing

0.01 MKCl

solution at

298 K

1750 Ω

. If the conductivity of

0.01 MKCl

solution at

298 K

0.152 \times 10^{- 3} S {cm}^{- 1}

, then the cell constant of the conductivity cell is____

\times 10^{- 3} {cm}^{- 1}

MEDIUM

Chemistry>Physical Chemistry>Electrochemistry>Conductance in Electrolytic Solutions

Let

C_{NaCl}

and

{C_{BaSO}}_{4}

, be the conductances (in S) measured for saturated aqueous solutions of

NaCl

and

B a S O_{4}

respectively, at a temperature T. Which of the following is false?

MEDIUM

Chemistry>Physical Chemistry>Electrochemistry>Conductance in Electrolytic Solutions

The resistance of a conductivity cell containing

0.001 MKCl

solution at

298 K

1500 Ω

. What is the cell constant if the conductivity of

0.001 MKCl

solution at

298 K

0.146 \times 10^{- 3} {Scm}^{- 1} .

MEDIUM

Chemistry>Physical Chemistry>Electrochemistry>Conductance in Electrolytic Solutions

The graph of

\sqrt{C} vs \land_{m}

for an aqueous solution of which substance is not obtained as a straight line?

MEDIUM

Chemistry>Physical Chemistry>Electrochemistry>Conductance in Electrolytic Solutions

On which of the following factor ionic conductivity of solution does not depend?

EASY

Chemistry>Physical Chemistry>Electrochemistry>Conductance in Electrolytic Solutions

What is the SI unit of conductivity?

EASY

Chemistry>Physical Chemistry>Electrochemistry>Conductance in Electrolytic Solutions

What is the common unit of conductivity if the dimensions are expressed in centimeter?

MEDIUM

Chemistry>Physical Chemistry>Electrochemistry>Conductance in Electrolytic Solutions

Distinguish between electronic conduction and electrolytic conduction.

EASY

Chemistry>Physical Chemistry>Electrochemistry>Conductance in Electrolytic Solutions

The decreasing order of electrical conductivity of the following aqueous solutions is:

(A)

0.1 M

Formic acid,

(B)

0.1 M

Acetic acid,

(C)

0.1 M

Benzoic acid.

MEDIUM

Chemistry>Physical Chemistry>Electrochemistry>Conductance in Electrolytic Solutions

Define conductance and give its unit.

EASY

Chemistry>Physical Chemistry>Electrochemistry>Conductance in Electrolytic Solutions

The specific conductance of an aqueous

{KNO}_{3}

solution at

298 K,

for a fixed concentration is

0.024 {ohm}^{- 1} {cm}^{- 1} .

If the resistance of a cell containing this solution at

298 K

was found to be

85 ohm,

then find its cell constant.

EASY

Chemistry>Physical Chemistry>Electrochemistry>Conductance in Electrolytic Solutions

_____ are the reason for the electrical conductance of sodium chloride in molten state.

HARD

Chemistry>Physical Chemistry>Electrochemistry>Conductance in Electrolytic Solutions

The equivalent conductance of

NaCl

at concentration C and at infinite dilution are

λ_{C}

and

λ_{\infty}

, respectively. The correct relationship between

λ_{C}

and

λ_{\infty}

is given as :
(where the constant B is positive)

HARD

Chemistry>Physical Chemistry>Electrochemistry>Conductance in Electrolytic Solutions

Resistance of 0.2 M solution of an electrolyte is

50 Ω

. The specific conductance of the solution is

{1.4 S m}^{-1}

. The resistance of 0.5 M solution of the same electrolyte is

280 Ω

. The molar conductivity of 0.5 M solution of the electrolyte in

{S m}^{2} {mol}^{-1}

is :

MEDIUM

Chemistry>Physical Chemistry>Electrochemistry>Conductance in Electrolytic Solutions

An electrolyte of a polymer-salt complex of poly (ethylene oxide) -

{LiCF}_{3} {SO}_{3}

is shaped into a free standing circular film of

20 mm

diameter and a thickness of

20 μ m .

When it is sandwiched between 2 stainless steel circular electrodes of the same diameter, this cell exhibits a conductance of

\frac{314}{5} S .

What is the specific conductivity of the electrolyte?

EASY

Chemistry>Physical Chemistry>Electrochemistry>Conductance in Electrolytic Solutions

Amongst the following, the form of water with the lowest ionic conductance at

298 K

is:

MEDIUM

Chemistry>Physical Chemistry>Electrochemistry>Conductance in Electrolytic Solutions

Give a reason for the following.
Conductivity of dilute hydrochloric acid is greater than that of acetic acid.

Express the relation among the conductivity of a solution in the cell, the cell constant and the resistance of the solution in the cell?

Important Questions on Electrochemistry

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