Consider the hypothetical situation where the azimuthal quantum number, l , takes values 0 , 1 , 2 , … … . . n + 1 . Where n is the principal quantum number. Then, the element with atomic number:

13 has a half-filled valence subshell

At temperature T , the average kinetic energy of any particle is 3 2 kT . The de Broglie wavelength follows the order:

Visible photon > thermal electron > thermal neutron.

Thermal neutron > visible photon > thermal electron.

Thermal neutron > thermal electron > visible photon.

Visible photon > thermal neutron > thermal electron.

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For a 4p orbital, the number of radial and angular nodes, respectively, are

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Important Questions on Structure of Atom

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Chemistry>Physical Chemistry>Structure of Atom>Quantum Mechanical Model of the Atom

The electrons are more likely to be found:
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Chemistry>Physical Chemistry>Structure of Atom>Quantum Mechanical Model of the Atom

C_{60}

emerging from a source at a speed (v) has a de Broglie wavelength of

11.0 Å

. The value of v (in m

s^{- 1}

) is closest to

[Planck's constant

h = 6.626 \times 10^{- 34} J s

]

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Chemistry>Physical Chemistry>Structure of Atom>Quantum Mechanical Model of the Atom

The quantum number of four electrons are given below:

I . n = 4, l = 2, m_{l} = - 2, m_{s} = - 1 / 2

I I . n = 3, l = 2, m_{l} = 1, m_{s} = + 1 / 2

I I I . n = 4, l = 1, m_{l} = 0, m_{s} = + 1 / 2

I V . n = 3, l = 1, m_{l} = 1, m_{s} = - 1 / 2

The correct order of their increasing energies will be:

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Chemistry>Physical Chemistry>Structure of Atom>Quantum Mechanical Model of the Atom

The graph between

{|ψ|}^{2}

and

r

(radical distance) is shown below. This represents:
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Chemistry>Physical Chemistry>Structure of Atom>Quantum Mechanical Model of the Atom

The correct set of four quantum numbers for the valence electrons of rubidium atom

(Z = 37)

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Which one of the following about an electron occupying the 1s orbital in a hydrogen atom is incorrect? (The Bohr radius is represented by

a_{0}

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Chemistry>Physical Chemistry>Structure of Atom>Quantum Mechanical Model of the Atom

A stream of electrons from a heat filament was passed between two charge plates kept at a potential difference

V esu

. If

e

and

m

are charge and mass of an electron, respectively, then the value of

\frac{h}{λ}

(where

λ

is wavelength associated with the electron wave) is given by:

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Chemistry>Physical Chemistry>Structure of Atom>Quantum Mechanical Model of the Atom

Two particles

A

and

B

are in motion. If the wavelength associated with

A

33.33 nm

, the wavelength associated with

B

whose momentum is

\frac{1}{3} rd

A

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Chemistry>Physical Chemistry>Structure of Atom>Quantum Mechanical Model of the Atom

The angular momentum of electron in

d

-orbital is equal to

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Chemistry>Physical Chemistry>Structure of Atom>Quantum Mechanical Model of the Atom

Which of the following pairs of

d -

orbitals will have the electron density along the axis?

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Chemistry>Physical Chemistry>Structure of Atom>Quantum Mechanical Model of the Atom

What is the maximum number of orbitals that can be identified with the following quantum number

n = 3, l = 1, m = 0

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Chemistry>Physical Chemistry>Structure of Atom>Quantum Mechanical Model of the Atom

Which of the following combination of statements is true regarding the interpretation of the atomic orbitals?

(A)

An electron in an orbital of high angular momentum stays away from the nucleus than an electron in the orbital of lower angular momentum.

(B)

For a given value of the principal quantum number, the size of the orbit is inversely proportional to the azimuthal quantum number.

(C)

According to wave mechanics, the ground state angular momentum is equal to

\frac{h}{2 π}

(D)

The plot of

ψ

r

for various azimuthal quantum numbers, shows peak shifting towards higher

r

value.

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The number of orbitals associated with quantum numbers

n = 5, m_{s} = + \frac{1}{2}

is:

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Chemistry>Physical Chemistry>Structure of Atom>Quantum Mechanical Model of the Atom

Among the following, the energy of

2 s

orbital is lowest in:

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Chemistry>Physical Chemistry>Structure of Atom>Quantum Mechanical Model of the Atom

The de Broglie wavelength of an electron in the

4^{t h}

Bohr's orbit of hydrogen is:

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Chemistry>Physical Chemistry>Structure of Atom>Quantum Mechanical Model of the Atom

Consider the hypothetical situation where the azimuthal quantum number,

l

, takes values

0, 1, 2, \dots \dots . . n + 1

. Where n is the principal quantum number. Then, the element with atomic number:

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Chemistry>Physical Chemistry>Structure of Atom>Quantum Mechanical Model of the Atom

The number of subshells associated with

n = 4

and

m = - 2

quantum numbers is:

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Chemistry>Physical Chemistry>Structure of Atom>Quantum Mechanical Model of the Atom

Maximum number of electrons that can be accommodated in the subshell with azimuthal quantum number

l = 4

is.

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Chemistry>Physical Chemistry>Structure of Atom>Quantum Mechanical Model of the Atom

At temperature

T

, the average kinetic energy of any particle is

\frac{3}{2} kT

. The de Broglie wavelength follows the order:

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Chemistry>Physical Chemistry>Structure of Atom>Quantum Mechanical Model of the Atom

Two electrons occupying the same orbital are distinguished by:

For a 4p orbital, the number of radial and angular nodes, respectively, are

Important Questions on Structure of Atom

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