MEDIUM
Earn 100

For a reaction of the type A+BX products, it is observed that doubling the concentration of A causes the reaction rate k1 to be four-times as great, but doubling the amount of B does not affect the rate k2. The rate equation is

A+B2AB+B. k1

A+BAB.... k2

50% studentsanswered this correctly

Important Questions on Chemical Kinetics

MEDIUM
For the reaction 2H2g+2NOgN2g+2H2Og the observed rate expression is, rate =kfNO2H2 . The rate expression for the reverse reaction is:
HARD
For the reaction 2N2O54NO2+O2, rate and rate constant are 1.02×104 mol lit1sec1 and 3.4 × 105sec1 respectively then concentration of N2O5 at that time will be
MEDIUM
For the following reactions

Question Image

where,

Question Image
ks and ke , are respectively, the rate constants for substitution and elimination, and μ=kske , the correct option is ________
EASY
Decomposition of X exhibits a rate constant of 0.05μg/year. How many years are required for the decomposition of 5μg of X into 2.5μg?
EASY
The rate law for the reaction below is given by the expression kA[B]

A+BProduct

If the concentration of B is increased from 0.1 to 0.3 mol, keeping the value of A at 0.1 mol, the rate constant will be:
EASY

Consider the following reactions
AP1;BP2;CP3;DP4
The order of the above reactions are a, b, c and d,respectively. The following graph is obtained when log[rate] vs.log[conc.] are plotted:

Question Image  
Among the following, the correct sequence for the order of the reactions is :

EASY
For a chemical reaction rate law is, rate =KA2B. If [A] is doubled at constant B, the rate of reaction.
MEDIUM
Which one of the following statements is not correct?
HARD
The reaction of ozone with oxygen atoms in the presence of chlorine atoms can occur by a two step process shown below:

O3g+ClO2g+ClOg ...(i)

ki=5.2×109 L mol-1 s-1

ClOg+OgO2g+Clg ...(ii)

kii=2.6×1010 L mol-1 s-1

The closest rate constant for the overall reaction

O3g+Og2O2g is:
EASY
NO2 required for a reaction is produced by the decomposition of N2O5 in CCl4 as per the equation,
2N2O5g4NO2g+O2g.
The initial concentration of N2O5 is 3.00 mol L-1 and it is 2.75 mol L-1 after 30 minutes. The rate of formation of NO2 is:
HARD

For an elementary chemical reaction, A2 k-1k12A , the expression for dAdt is:

MEDIUM
Find the unit of the rate constant of a reaction represented with a rate equation, rate =kA12 B32
EASY

Which of the following expression is correct for the rate of reaction given below ?

5Br-aq+BrO3-aq+6H+aq3Br2aq+3H2Ol

HARD

The results given in the below table were obtained during kinetic studies of the following reaction: 2A+BC+D

Experiment A/molL-1 B/molL-1 Initial rate/molL-1min-1
I 0.1 0.1 6.00×10-3
II 0.1 0.2 2.40×10-2
III 0.2 0.1 1.20×10-2
IV X 0.2 7.20×10-2
V 0.3 Y 2.88×10-1

X and Y in the given table are respectively :

MEDIUM
The rate constant for a second order reaction, A Product, is 1.62 M-1 s-1. What will be the rate of reaction when concentration of reactant is 2×10-3M?
EASY
The unit of second order reaction rate constant is;
EASY
For a first order reaction (AP) the rate constant is 5×10-3 min-1 when the initial concentration of A=2×10-2 M. If the initial concentration of A is doubled, what will be the rate constant (in min-1) at the same temperature?
MEDIUM

In the following reaction; xAyB

log10-dAdt=log10-dBdt+0.3010

‘A’ and ‘B’ respectively can be:

MEDIUM
Mechanism of a hypothetical reaction X2+Y22XY is given below:

(i) X2X+X fast

(ii) X+Y2XY+Y slow

(iii) X+YXY fast

The overall order of the reaction will be
EASY
A+2BC , the rate equation for the reaction is given as

Rate =k[A][B]

If the concentration of A is kept the same but that of B is doubled what will happen to the rate itself?