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For the reaction, , the correct option is
(a) and
(b) and
(c) and
(d) and

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Important Questions on Thermodynamics
MEDIUM
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The correct option for free expansion of an ideal gas under adiabatic condition is

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Under the isothermal condition, a gas at expands from to against a constant external pressure of bar. The work done by the gas is
(Given that bar)

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In which case change in entropy is negative?

HARD
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The bond dissociation energies of and are in the ratio of for the formation of is . What will be the bond dissociation energy of ?

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A gas is allowed to expand in a well-insulated container against a constant external pressure of from an initial volume of to a final volume of The change in internal energy of the gas in joules will be

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For a given reaction, and The reaction is spontaneous at : (Assume that and do not vary with temperature)

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For a sample of perfect gas, when its pressure is changed isothermally from to , the entropy change is given by

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The correct thermodynamic conditions for the spontaneous reaction at all temperatures is:
