HARD
Earn 100

Given,

λ of 0.01 M MgCl2 is 220 S cm2 mol-1

λ° of MgCl2 is 240 S cm2 mol-1

λ° of Mg2+ is 100 S cm2 mol-1

All above measurements are done in an electrolytic cell. Assuming MgCl2 to be a strong electrolyte which of the following is/are incorrect?

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Important Questions on Electrochemistry

MEDIUM
0.002M solution of a weak acid has an equivalent conductance (Λ)60ohm-1 cm2eq-1. What will be the pH ? (Given : Λ°=400ohm-1 cm2eq-1 ]
HARD
The equivalent conductance of NaCl at concentration C and at infinite dilution are λ C and λ , respectively. The correct relationship between λ C and λ is given as :
(where the constant B is positive)
MEDIUM
Why can limiting molar conductivity of CH3COOH  not be determined experimentally ?
 
HARD
Choose the correct representation of conductometric titration of benzoic acid vs sodium hydroxide.
HARD
State and explain kohlrausch's law of independent migration of ions.
MEDIUM

The molar conductivity of 0.007 M acetic acid is 20 S cm2 mol-1. What is the dissociation constant of acetic acid? Choose the correct option.

λH+=350 S cm2 mol-1λCH3COO-=50 S cm2 mol-1

EASY

Following figure shows dependence of molar conductance of two electrolytes on concentration. Λm0 is the limiting molar conductivity.

Question Image

 

The number of Incorrect statement(s) from the following is _____

(A) Λm0 for electrolyte A is obtained by extrapolation
(B) For electrolyte B,   Λm Vs c  graph is a straight line with intercept equal to Λm0
(C) At infinite dilution, the value of degree of dissociation approach zero for electrolyte B.
(D) Λm for any electrolyte A or B can be calculated using λ° for individual ions.

HARD
mo for NaCl,HCl and NaA are 126.4,425.9 and 100.5Scm2mol-1 respectively. If the conductivity of 0.001MHA is 5×10-5 S cm-1, degree of dissociation of HA is
EASY
Λm0 values for NaCl,HCl and CH3COONa are 126.4 S cm2 mol-1, 425.9 S cm2 mol-1 and 91.0 S cm2 mol-1 respectively. Λm0 value for CH3COOH is
MEDIUM

Calculate the degree of dissociation () of acetic acid, if its molar conductivity (Ʌm) is 39.05 S cm2 mol-1

Given: λ°(H+)=349.6 S cm2 mol-1 and λ°(CH3COO-)=40.9 S cm2 mol-1.

MEDIUM
The conductivity of a weak acid HA of concentration 0.001 mol L-1 is 2.0×10-5 S cm-1. If Λm0(HA)=190 S cm2 mol-1, the ionization constant Ka of HA is equal to ____ ×10-6
(Round off to the Nearest Integer)
MEDIUM
λ°m for NH4Cl, NaOH and NaCl are 130, 248 and 126. 5 ohm-1em2mo-1 respectively. The λ°m NH4OH will be,
EASY

The molar conductance of NaCl, HCl and CH3COONa at infinite dilution are 126.45, 426.16 and 91.0 Scm2 mol-1 respectively. The molar conductance of CH3COOH at infinite dilution is. Choose the right option for your answer.

HARD

Plotting 1/Λm against m for aqueous solutions of a monobasic weak acid (HX) resulted in a straight line with y-axis intercept of P and slope of S. The ratio P/S is
Λm= molar conductivity 

Λmo= limiting molarconductivity   c= molarconcentration

Ka= dissociation constant of HX

MEDIUM
The limiting molar conductivities of NaI,NaNO3 and AgNO3 are 12.7,12.0 and 13.3 mSm2 mol-1, respectively (all at 25 °C). The limiting molar conductivity of AgI at this temperature is____mSm2 mol-1.
EASY
Aqueous solution of which of the following compounds is the best conductor of electric current?