MEDIUM
12th West Bengal Board
IMPORTANT
Earn 100

Given the standard electrode potentials,

K+/K=-2.93 V;

Ag+/Ag=0.80 V;

Hg2+/Hg=0.79 V;

Mg2+/Mg=-2.37 V;

Cr3+/Cr=0.74 V

Arrange these metals in their increasing order of reducing power:

Important Questions on Electrochemistry

MEDIUM
12th West Bengal Board
IMPORTANT

 Arrange the following metals in the order in which they displace each other from the solution of their salts:

Al, Cu, Fe, Mg, Zn

HARD
12th West Bengal Board
IMPORTANT

Calculate the e.m.f. of the cell ZnZn2+0.1MCu2+0.01MCu

EZn2+/ZnΘ=-0.76 V and ECu2+/CuΘ=0.34 V

HARD
12th West Bengal Board
IMPORTANT

Calculate the E.M.F. of the following cell at 298 K:

MgMg2+0.130MAg+1.0×10-4MAg

Given that EMg2+MgΘ=-2.37 V, EAg+AgΘ=0.80 V

HARD
12th West Bengal Board
IMPORTANT
Find the pH of following acid solution Pt, H21 barH+aq. acidH+1 MH2g, 1 bar, Pt . The measured e.m.f. of the cell =0.182 V.
HARD
12th West Bengal Board
IMPORTANT
In the cell reaction, 4Cr2+aq+O2g+4H+aq4Cr3+(aq)+2H2Ol, the concentrations are: Cr2+=0.1 M, Cr3+=0.082 M, H+=0.01 M. Find the partial pressure of O2 gas at equilibrium at 25°C.ECr3+/Cr2+Θ=-0.41 V. EO2/H2OΘ=1.23 V
HARD
12th West Bengal Board
IMPORTANT

Calculate the equilibrium constant K for the reaction at 298 K:

Zns+Cu2+aqZn2+aq+Cus [Given EZn2+/Zn°=-0.76 V; ECu2+/Cu°=0.34 V]

HARD
12th West Bengal Board
IMPORTANT

Calculate the equilibrium constant for the following cell reaction.

12Cl2g+Br-12Br2l+Cl-; E°=0.30 V

HARD
12th West Bengal Board
IMPORTANT

Calculate the value of ΔG and Ecell at 298 K for the following cell.

AlAI(0.01M)3+Fe(0.02M)2+Fe

Given that EAl3+/AlΘ=-1.66 V and EFe2+/FeΘ=0.80 V