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Higher order reactions are rare due to
(a)Shifting of equilibrium towards reactants due to elastic collisions
(b)Loss of active species on collision
(c)Low probability of simultaneous collision of all reacting species
(d)Increase in entropy as more molecules are involved

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Important Questions on Chemical Kinetics
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For an elementary reaction the rate of appearance of at time is . Rate of disappearance of at , will be

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For the reaction, , The rate of disappearance of is . The rate of appearance of is

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of is mixed with of to form an ester. The rate of the reaction with respect to the initial rate when each solution is diluted with an equal volume of water will be

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The rate of a gaseous reaction is given by the expression If the volume of vessel is reduced to one half of the initial volume, the reaction rate as compared to original rate is

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The time required for completion of a first order reaction is . The time required for completion of the same reaction will be

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The plot of v/s for a reaction is a straight-line parallel to -axis. The unit for the rate constant of this reaction is

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The value of rate constant of a pseudo-first-order reaction

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If the rate constant for a first order reaction is the time required for the completion of of the reaction is given by
