HARD
JEE Main
IMPORTANT
Earn 100

How can the reduction potential of an electrode MsMn+aq be increased?

Important Questions on Electrochemistry

MEDIUM
JEE Main
IMPORTANT
The equilibrium constant is related to E°cell  but not to Ecell . Explain why.
EASY
JEE Main
IMPORTANT
What is the free energy change for (a) galvanic cell (b) electrolytic cell?
HARD
JEE Main
IMPORTANT
An excess of solid AgCl is added to a 0.1 M solution of Br- ions at 298 K. Calculate the concentrations of Cl- and Br- ions at equilibrium. Given: E°Cl-/AgCl/Ag=0.222 V and E°Br-/AgBr/Ag=0.095 V?
MEDIUM
JEE Main
IMPORTANT

Find the solubility product of a saturated solution of Ag2CrO4 in water at 298 K if the EMF of the cell Ag|Ag+(saturated Ag2CrO4 solution)||Ag+(0.1 M)|Ag is 0.164 V at 298 K?

EASY
JEE Main
IMPORTANT

In the electrochemical cell,

MgsMg2+aqZn2+aqZns; E°=+3.13 V

The correct plot of Ecell  versus logMg2+Zn2+ will be represented as

MEDIUM
JEE Main
IMPORTANT

The overall cell reaction of Daniel cell is:
Zn s+Cu2+Zn2++Cu s; E0=+1.10 V

Q=Zn2+Cu2+

When log10Q is plotted on the X-axis and Ecell  on the Y-axis, which of the following will correctly represent the variation?

HARD
JEE Main
IMPORTANT
An alloy of Pb-Ag weighing 1.08 g was dissolved in dilute HNO3 and the volume was made to 100 mL. A silver electrode was dipped in the solution and the EMF of the cell set-up, Pts,H2g1 atm H+aq 1 M  Ag+aq Ags was 0.62 V. If Ecello is 0.80 V, what is the percentage of Ag in the alloy? At 25°C, 2.303RT/F=0.06
HARD
JEE Main
IMPORTANT
Determine the solubility product of Co2FeCN6 in water at 25°C from the following data: Conductivity of saturated solution of Co2FeCN6=2.06×10-6ohm-1cm-1 and that of water =4.1×10-7 ohm-1cm-1. The ionic molar conductivities of Co2+ and FeCN64 are 86 and 444 ohmcm2-1mol-1, respectively?