EASY
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How do you explain with the help of a graph, the increase in the value of molar conductivity with dilution in case of strong and weak electrolyte?

Important Questions on Electrochemistry

EASY
Consider the statements S1 and S2 :
S1 : Conductivity always increases with decreases in the concentration of electrolyte.
S2 : Molar conductivity always increases with decreases in the concentration of electrolyte.
The correct option among the following
EASY
What is meant by 'limiting molar conductivity' 
HARD
mo for NaCl,HCl and NaA are 126.4,425.9 and 100.5Scm2mol-1 respectively. If the conductivity of 0.001MHA is 5×10-5 S cm-1, degree of dissociation of HA is
MEDIUM

In the plot of molar conductivity(m)  vs square root of concentration (c1/2), following curves are obtained for two electrolytes A and B :

Question Image

Answer the following :

What happens on extrapolation of m to concentration approaching zero for electrolytes A and B ?

MEDIUM

Given below are two statements:

Statement I: For KI, molar conductivity increases steeply with dilution.

Statement II: For carbonic acid, molar conductivity increases slowly with dilution. In the light of the above statements, choose the correct answer from the options given below

MEDIUM
Define conductivity of an electrolytic solution. How does it vary with decrease in concentration and why?
EASY
If the molar conductivities in S cm2 mol-1 of NaCl, KCl and NaOH  at infinite dilution are 126 and 150 and 250 respectively, the molar conductivity of KOH in S cm2 mol-1 is -
EASY
Why does the conductivity of a solution decrease with dilution?
EASY
The molar conductivity of NaCl, CH3COONa and HCl at infinite dilution is 126.45, 91.0 and 426.16 ohm-1cm2mol-1 respectively. Calculate the molar conductivity (λm) for CH3COOH at infinite dilution.
MEDIUM
The molar conductivity of a 0.5 mol dm-3 solution of AgNO3 with electrolytic conductivity of 5.76×10-3 S cm-1 at 298 K
MEDIUM
Ionic mobility of Ag+ is λAg+=5×10-1 ohm-1 cm2 eq-1
EASY
The specific conductance K of 0.02 M aqueous acetic acid solution at 298 K is 1.65×10-4Scm-1. The degree of dissociation of acetic acid is

[Given: equivalent conductance at infinite dilution of H+=349.1Scm2mol-1 and CH3COO-=40.9Scm2  mol-1 ]
MEDIUM
What is meant by limiting molar conductivity?
MEDIUM
Give a reason for the following.
Conductivity of dilute hydrochloric acid is greater than that of acetic acid.
MEDIUM
The molar conductivities of HCl, NaCl, CH3COOH and CH3COONa at infinite dilution follow the order
EASY
Why limiting molar conductivity of CH3COOH cannot be determined experimentally?
MEDIUM
Give reason: Conductivity of CH3COOH decreases on dilution.
MEDIUM
Which of the following electrolytic solution has the least specific conductance