A piston filled with 0.04 mol of an ideal gas expands reversibly from 50.0 mL to 375 mL at a constant temperature of 3 7 . 0 ∘ C . As it does so, it absorbs 208 J of heat. The values of q and w for the process will be (R = 8.314 J/mol K) (ln7.5 = 2.01)

q = + 2 0 8 J , w ⁡ = - 2 0 8 J

q = + 2 0 8 J , w ⁡ = + 2 0 8 J

q = - 2 0 8 J , w ⁡ = - 2 0 8 J

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If an element in group $2$ formed a compound with an element in group $17$ of the periodic table, the compound formed is likely to _______

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Important Questions on Solid State

MEDIUM

Chemistry>Physical Chemistry>Solid State>Classification and Properties of Solids

A piston filled with 0.04 mol of an ideal gas expands reversibly from 50.0 mL to 375 mL at a constant temperature of

37 . 0^{\circ} C

. As it does so, it absorbs 208 J of heat. The values of q and w for the process will be
(R = 8.314 J/mol K) (ln7.5 = 2.01)

MEDIUM

Chemistry>Physical Chemistry>Solid State>Classification and Properties of Solids

The combination of plots which does not represent isothermal expansion of an ideal gas is

$(A)$ Question Image

$(B)$

$(C)$

$(D)$

HARD

Chemistry>Physical Chemistry>Solid State>Classification and Properties of Solids

The above

P - V

diagram represents the thermodynamic cycle of an engine, operating with an ideal mono-atomic gas. The amount of heat, extracted from the source in a single cycle, is:

EASY

Chemistry>Physical Chemistry>Solid State>Classification and Properties of Solids

Calculate the work done during compression of

2

mol of an ideal gas from a volume of

1 m^{3}

10

{dm}^{3}

300 K

against a pressure of

100 kPa

EASY

Chemistry>Physical Chemistry>Solid State>Classification and Properties of Solids

Which of the following statements is true with regards to crystalline solids?

EASY

Chemistry>Physical Chemistry>Solid State>Classification and Properties of Solids

The work done during combustion of

9 \times 10^{- 2}

kg

of ethane,

C_{2} H_{6} (g)

300 K

is (Given

R = 8 .314 {JK}^{- 1} {mol}^{- 1}

, atomic mass

C = 12, H = 1

)

HARD

Chemistry>Physical Chemistry>Solid State>Classification and Properties of Solids

A reversible cyclic process for an ideal gas is shown below. Here,

P, V, a n d T

are pressure, volume and temperature, respectively. The thermodynamic parameters

q, w, H a n d U

are heat, work, enthalpy and internal energy, respectively.

Question Image

The correct option(s) is (are)

MEDIUM

Chemistry>Physical Chemistry>Solid State>Classification and Properties of Solids

For the isothermal reversible expansion of an ideal gas

EASY

Chemistry>Physical Chemistry>Solid State>Classification and Properties of Solids

A piece of ice falls from a height

h

so that it melts completely. Only one-quarter of the heat produced is absorbed by the ice and all energy of ice gets converted into heat during its fall. The value of

h

is:
(Latent heat of ice is

3.4 \times 10^{5} {J kg}^{- 1}

and

g = 10 {N kg}^{- 1}

)

MEDIUM

Chemistry>Physical Chemistry>Solid State>Classification and Properties of Solids

The qualitative sketches I, II and III given below show the variation of surface tension with molar concentration of three different aqueous solutions of KCl,

C H_{3} O H

and

C H_{3} {(C H_{2})}_{11} O S O_{3}^{-} N a^{+}

at room temperature. The correct assignment of the sketches is -

Question Image

MEDIUM

Chemistry>Physical Chemistry>Solid State>Classification and Properties of Solids

X g

of ice at

0^{o} C

is added to 340g of water at

20^{o} C

. The final temperature of the resultant mixture is

5^{o} C

. The value of

X

(in g) is closest to

[Heat of fusion of ice

= 333 J / g

; Specific heat of water

= 4.184 J / g . K

]

MEDIUM

Chemistry>Physical Chemistry>Solid State>Classification and Properties of Solids

Select the correct statements.
(A) Crystalline solids have long range order.
(B) Crystalline solids are isotropic.
(C) Amorphous solid are sometimes called pseudo solids.
(D) Amorphous solids soften over a range of
temperatures.
(E) Amorphous solids have a definite heat of fusion. Choose the most appropriate answer from the options given below.

EASY

Chemistry>Physical Chemistry>Solid State>Classification and Properties of Solids

A gas undergoes change from state

A

to state

B

. In this process, the heat absorbed and work done by the gas is

5 J and 8 J

, respectively. Now gas is brought back to

A

by another process during which

3 J

of heat is evolved. In this reverse process of

B to A

MEDIUM

Chemistry>Physical Chemistry>Solid State>Classification and Properties of Solids

A system consisting of 1 mol of an ideal gas undergoes a reversible process,

A \to B \to C \to A

(schematically indicated in the figure below). If the temperature at the starting point A is 300 K and the work done in the process

B \to C

is 1 L atm, the heat exchanged in the entire process in L atm is

Question Image

EASY

Chemistry>Physical Chemistry>Solid State>Classification and Properties of Solids

An ideal gas undergoes isothermal expansion at constant pressure. During the process:

HARD

Chemistry>Physical Chemistry>Solid State>Classification and Properties of Solids

The volume vs. temperature graph of 1 mole of an ideal gas is given below

Question Image

The pressure of the gas (in atm) at

X, Y

and

Z,

respectively, are

MEDIUM

Chemistry>Physical Chemistry>Solid State>Classification and Properties of Solids

A gas is allowed to expand in a well-insulated container against a constant external pressure of

2.5 atm

from an initial volume of

2.50 L

to a final volume of

4.50 L .

The change in internal energy

ΔU

of the gas in joules will be

HARD

Chemistry>Physical Chemistry>Solid State>Classification and Properties of Solids

An ideal gas undergoes isothermal compression from

5 m^{3}

1 m^{3}

against a constant external pressure of

4 N m^{- 2}

. The heat released in this process is

24 J {mol}^{- 1} K^{- 1}

and is used to increase the pressure of

1

mole of

Al

. The temperature of

Al

increases by:

MEDIUM

Chemistry>Physical Chemistry>Solid State>Classification and Properties of Solids

Given below are two statements. One is labelled as
Assertion $A$ and the other is labelled as Reason $R$ .
Assertion $A :$ Sharp glass edge becomes smooth on heating it up to its melting point.

Reason $R :$ The viscosity of glass decreases on melting.

Choose the most appropriate answer from the options given below.

EASY

Chemistry>Physical Chemistry>Solid State>Classification and Properties of Solids

The amorphous form of silica is:

If an element in group 2 formed a compound with an element in group 17 of the periodic table, the compound formed is likely to _______

Important Questions on Solid State

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If an element in group $2$ formed a compound with an element in group $17$ of the periodic table, the compound formed is likely to _______