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In a market with a fixed number of firms, if the market price is above the equilibrium price, what would be the result?

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Important Questions on Equilibrium

EASY

A solid XY kept in an evacuated sealed container undergoes decomposition to form a mixture of gases X and Y at temperature T.

The equilibrium pressure is 10 bar in this vessel. Kp for this reaction is?

HARD
4.0 moles of argon and 5.0 moles of PCl5 are introduced into an evacuated flask of 100 litre capacity at 610 K. The system is allowed to equilibrate. At equilibrium, the total pressure of mixture was found to be 6.0 atm. The Kp for the reaction is [Given : R=0.082 L atm K-1 mol-1 ]
EASY
If the equilibrium constant for N2g+O2(g)2NO(g) is K, the equilibrium constant for 12N2g+12O2(g)NO(g) will be:
MEDIUM
For the reaction:   2NO2g2NOg+O2g, 

Kc=1.8×10-6 at 184oCR=0.0831J/molK

When  Kp and Kc are compared at 184oC. It is found that
MEDIUM
At 60°C, dinitrogen tetroxide is fifty percent dissociated. Find its standard free energy change at this temperature and one atmosphere. [ Given: log1.33=0.1239 ]
HARD

A(g)2 B( g)+C(g)

For the given reaction, if the initial pressure is 450 mmHg and the pressure at time t is 720 mmHg at a constant temperatureT and constant volume V. The fraction of A(g) decomposed under these conditions is x×10-1. The value of x is (nearest integer)

EASY
Consider the following reversible chemical reactions:

A2g+B2gk12ABg .....(1)  

6ABgk23A2g+3B2g .....(2)

The relation between K1 and K2 is:
HARD

For a reaction at equilibrium

 AgBg+12Cg

 the relation between dissociation constant K, degree of dissociation α and equilibrium pressure p is given by :

HARD
For the reaction AgBg+Cg, A is 33% dissociated at a total pressure P. The correct relation between P and Kp is
MEDIUM

For the reaction

H2g+CO2gCOg+H2Og, if the initial concentration of H2=CO2 = 1M and x moles/L of H2 is consumed at equilibrium, the correct expression of KP is.

EASY
For NH4HSsNH3g+H2 Sg  the
observed pressure for the reaction mixture in equilibrium is 1.12 atm at 106°C. What is the value of Kp for the reaction?
MEDIUM
A sample of HI(g) is placed in a flask at a pressure of 0.2 atm. At equilibrium, partial pressure of HI(g) is 0.04 atm. What is Kp for the given equilibrium ? 2HI(g)H2( g)+I2(g)
HARD
A 20 litre container at 400 K contains CO2g at pressure 0.4 atm and an excess of SrO (neglect the volume of solid SrO ). The volume of the container is now decreased by moving the movable piston fitted in the container. The maximum volume of the container, when the pressure of CO2 attains its maximum value, will be:

Given that:SrCO3sSrOs+CO2g, Kp=1.6 atm
MEDIUM
What do you understand by dynamic nature of chemical equilibrium? Give one experiment to prove that equilibrium is dynamic in nature.
MEDIUM

Which of the following statements is correct?

EASY
List any four important characteristics of a chemical equilibrium.
EASY
What do you understand by chemical equilibrium? Explain with one suitable example.
MEDIUM

Question ImageQuestion Image

Among the following points indicated on the graph, which one represents equilibrium?

EASY
Define 'homogeneous equilibria and heterogeneous equilibria'. Give three examples of each of them.