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In an SN1 reaction, the configuration of the product undergoes:

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Important Questions on Organic Chemistry- Some Basic Principles and Techniques

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The relative reactivity of acyl compounds towards nucleophilic substitution are in the order of: 
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The major product obtained on the mono-bromination (with Br2/FeBr3) of the following compound A is:

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The correct increasing order of reactivity for the following molecules towards electrophilic aromatic substitution is:

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Assertion (A) : Presence of nitro group facilitates nucleophlic substitution reactions in aryl halides.

Reason (R) : The intermediate carbocation is stable due to presence of nitro group.    

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Enthalpy of hydrogenation of cyclohexene is 119.5 kJ mol1. If resonance energy of benzene is 150.4 kJ mol1, its enthalpy of hydrogenation would be