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In the presence of dry ether, formaldehyde A undergoes nucleophilic addition with Grignard reagent (obtained from methyl iodide and metallic magnesium) to give compound B''. The compound B'' on heating with diazomethane in the presence of fluoroboric acid gives compound C''. Identify compounds B'' and C''.

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Important Questions on Organic Reactions

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Compound 'A' undergoes auto oxidation in the presence of cobalt naphthenate as catalyst at 423K in alkaline medium followed by heating with dil. H2SO4 to give compound 'B' and acetone as byproduct of the reaction. Compound 'B' is isolated by distillation and further heated with the nitrating mixture giving picric acid. Identify the compounds 'A' and 'B'.
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n-Propyl bromide A when boiled with aqueous KOH undergoes hydrolysis forming compound 'B'. The compound 'B' reacts with concentrated sulphuric acid at 443 K to yield compound 'C'. Identify the compounds 'B' and 'C'.
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Benzene azo-βnaphthol is an orange red dye widely used in textile industry for dyeing purpose. What are the structures of the reactants needed to prepare this dye?

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A mixed ether on heating with dilute H2SO4 under pressure, gives mixture of two alcohols, viz., methanol and ethanol. In this reaction, 80% yield of each alcohol is obtained. If the mass obtained for ethanol is 1.5 g, calculate the mass of the mixed ether used for the reaction.
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The compound 'A', i.e., butyronitrile is subjected to the Stephen reaction by using SnCl2 and dilute HCl, followed by the acid hydrolysis to give compound 'B', which is having a buttery odour, and it is used in margarine. The addition of hydrogen cyanide to the compound 'B', in the presence of a small amount of base, gives compound 'C'. Identify the compounds 'B' and 'C'.