EASY
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In which of the following decreases if there can be some intramolecular rearrangement?
(a)

(b)

(c)

(d)


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Important Questions on Organic Chemistry- Some Basic Principles and Techniques
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Which of the following carbocations is most stable?

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The compound that is most difficult to protonate is:

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The lower stability of ethyl anion compared to methyl anion and the higher stability of ethyl radical compared to methyl radical, respectively, are due to

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The correct order of stability of given carbocation is:

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The order of stability of the following carbocations:


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Choose the correct statement regarding the formation of carbocations A and B given :-

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For the following carbocations, the correct order of stability is
I.
II.
III.

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Assertion (A): Tertiary carbocations are more reactive than secondary and primary carbocations.
Reason (R): Hyper conjugation, as well as inductive effect due to additional alkyl groups stabilise tertiary carbocations.

HARD
A solution of in toluene racemises slowly in the presence of a small amount of SbCl5, due to the formation of :

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In which of the following compounds, the bond ionization shall give most stable carbonium ion?

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The most stable carbocation among the following is

HARD
The major products and in the following reactions are

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The decreasing order of the stability of the following carbocations is

MEDIUM
The stability order of the above carbocations is

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The decreasing order of stability of the given carbocations is


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Carbocations are important intermediates in organic reactions, they are often stabilised by resonance, inductive effect and hyperconjugation. The cation that can be stabilised by hyperconjugation is

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Consider the following carbocations
(a)
(b)
(c)
(d)
The stability sequence follows the order

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The stability of carbocations
follows the order

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Define ambident nucleophile with an example.

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The correct sequence of reagents for the following conversion will be


