EASY
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In which of the following Δ G  decreases if there can be some intramolecular rearrangement?

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Important Questions on Organic Chemistry- Some Basic Principles and Techniques

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The lower stability of ethyl anion compared to methyl anion and the higher stability of ethyl radical compared to methyl radical, respectively, are due to
 
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Choose the correct statement regarding the formation of carbocations A and B given :-

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EASY
For the following carbocations, the correct order of stability is
I. CH2-COCH3
II. CH2-OCH3
III. CH2-CH3
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Assertion (A): Tertiary carbocations are more reactive than secondary and primary carbocations.

Reason (R): Hyper conjugation, as well as inductive effect due to additional alkyl groups stabilise tertiary carbocations.

HARD
A solution of (-)1-chloro-1-phenylethane in toluene racemises slowly in the presence of a small amount of SbCl5, due to the formation of :
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In which of the following compounds, the C-Cl bond ionization shall give most stable carbonium ion?
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Carbocations are important intermediates in organic reactions, they are often stabilised by resonance, inductive effect and hyperconjugation. The cation that can be stabilised by hyperconjugation is
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Consider the following carbocations

(a) Cl3C+

(b) Cl2CH+

(c) ClCH2+

(d) CH3+

The stability sequence follows the order