HARD
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It is observed that five hours are needed to dissolve a 1 cm cube of NaCl in large amount of water. Calculate the time required for dissolution, if the cube is ground to a power containing 1016 equal sized spheres. Assume that the rate of dissolution is directly proportional to initial area of contact between NaCl and water.

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Important Questions on Surface Chemistry

MEDIUM
For a linear plot of log xm versus log p in a Freundlich adsorption isotherm, which of the following statements is correct? (k and n are constants)
MEDIUM
Which of the following is not applicable to the phenomenon of adsorption?
MEDIUM
What is an adsorption isotherm? Describe Freundlich adsorption isotherm.
MEDIUM
Adsorption of a gas follows Freundlich adsorption isotherm. x is the mass of the gas adsorbed on mass m of the adsorbent. The plot of logxm vs  logp  is shown in the given graph. xm is proportional to,
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EASY
Which of the following statements is incorrect regarding physisorption ?
EASY
A particular adsorption process has the following characteristics: (i) It arises due to van der Waals forces and (ii) it is reversible. Identify the correct statement that describes the above adsorption process:
EASY
Adsorption of gas on a surface follows Freundlich adsorption isotherm. The plot of logxm versus logP gives a straight line with slope equal to 0.5, then:

(xm is the mass of the gas adsorbed per gram of adsorbent)
HARD
Describe factors affecting adsorption of gases on solids.
EASY
The following statements relate to the adsorption of gases on a solid surface. Identify the incorrect statement among them:
EASY
Which one of the following is not a property of physical adsorption?
MEDIUM
10 mL of 1 mM surfactant solution forms a monolayer covering 0.24 cm2 on a polar substrate. If the polar head is approximated as a cube, what is its edge length?
EASY
Which one of the following characteristics is associated with adsorption?
EASY
A gas undergoes physical adsorption on a surface and follows the given Freundlich adsorption isotherm equation
xm=kp0.5
Adsorption of the gas increases with:
HARD
When O2 is adsorbed on a metallic surface, electron transfer occurs from the metal to O2 . The TRUE statement(s) regarding this adsorption is(are)
EASY
Which of the following statements is correct for the spontaneous adsorption of a gas?
HARD

The mass of gas adsorbed, x, per unit mass of adsorbate, m, was measured at various pressures, p. A graph between log xm and log p gives a straight line with slope equal to 2 and the intercept equal to 0.4771. The value of xm at a pressure of 4 atm is :

(Given log 3=0.4771)

MEDIUM
Amongst the following statements regarding adsorption, those that are valid are:
(a) ΔH becomes less negative as adsorption proceeds.
(b) On a given adsorbent, ammonia is adsorbed more than nitrogen gas.
(c) On adsorption, the residual force acting along the surface of the adsorbent increases
(d) With the increase in temperature, the equilibrium concentration of adsorbate increases.
EASY
Methylene blue, from its aqueous solution, is adsorbed on activated charcoal at 25o C. For this process, the correct statement is 
MEDIUM

Given:

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On the basis of data given above, predict which of the following gases shows the least adsorption on a definite amount of charcoal?

MEDIUM
3 g of activated charcoal was added to 50 mL of acetic acid solution (0.06 N) in a flask. After an hour, it was filtered and the strength of the filtrate was found to be 0.042 N. The amount of acetic acid adsorbed (per gram of charcoal) is: