Liquids $\mathrm{A}$ and $\mathrm{B}$ form ideal solution for all compositions of $\mathrm{A}$ and $\mathrm{B}$ at ${25}^{\circ }C$. Two such solutions with $0.25$ and $0.50$ mole fractions of $\mathrm{A}$ have the total vapor pressures of $0.3$ and $0.4$ bar, respectively. What is the vapor pressure of pure liquid $\mathrm{B}$ in bar?

In thermodynamics, the $\mathrm{P}-\mathrm{V}$ work done is given by $\mathrm{w}=-\int {\mathrm{dVP}}_{\mathrm{ext}}$. For a system undergoing a particular process, the work done is,

$\mathrm{w}=-\int \mathrm{dV}\left(\frac{\mathrm{RT}}{\mathrm{V}-\mathrm{b}}-\frac{\mathrm{a}}{{\mathrm{V}}^2}\right)$. This equation is applicable to a

If the distribution of molecular speeds of a gas is as per the figure shown below, then the ratio of the most probable, the average, and the root mean square speeds, respectively, is