Maximum change in percentage of $\%\mathrm{s}$-character of bonding orbital of central atom occurs in which of the following transformations (consider the underlined atom)?

In which of the following carbon--carbon single bond, length is the shortest?

Consider the following statement(s) for $°{\mathrm{CH}}_3=\mathrm{X}$ and $\dot{\mathrm{C}}{\mathrm{F}}_3=\mathrm{Y}$'

($\mathrm{I}$) When $\mathrm{X}$ dimerises, bond angle decreases

($\mathrm{II}$) When $\mathrm{X}$ dimerises, bond angle increases

($\mathrm{III}$) In $\mathrm{X}-\mathrm{Y}$ molecule, $\mathrm{C}-\mathrm{C}$ bond length is less than that in $\mathrm{Y}-\mathrm{Y}$ molecule

($\mathrm{IV}$) Bond angle in $\mathrm{X}$ is greater than that in $\mathrm{Y}$. Pick the incorrect statements.

 Match column $\mathrm{I}$ with column $\mathrm{II}$ and select the correct answer.