MEDIUM
Earn 100

Molar mass of the salt from NaBr, NaNO3, KI and CaF2 which does not evolve coloured vapours on heating with concentrated H2SO4 is ____ g mol1, (Molar mass in g mol1 : Na : 23, N : 14, K : 39, O : 16, Br : 80, I : 127, F : 19, Ca : 40)

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Important Questions on Inorganic Qualitative Analysis

HARD
A white precipitate was formed when BaCl2 was added to water extract of an inorganic salt. Further, a gas 'X' with characteristic odour was released when the formed white precipitate was dissolved in dilute HCI. The anion present in the inorganic salt is:
MEDIUM

Match List I with List II.

  List-I
(Anion)
  List-II
(gas evolved on reaction with dil. H2SO4)
(A) CO32- (I)

Colourless gas which turns lead acetate paper black.

(B) S2- (II)

Colourless gas which turns acidified potassium dichromate solution green.

(C) SO32- (III) Brown fumes which turns acidified KI solution containing starch blue.
(D) NO2- (IV) Colourless gas evolved with brisk effervescence, which turns lime water milky.

Choose the correct answer from the options given below

MEDIUM
The sodium salt of an organic acid X produces effervescence with concentrated H2SO4. X reacts with the acidified aqueous CaCl2 solution to give a white precipitate which decolourises acidic solution of KMnO4. X is
HARD
A test tube contain the acidic radical P. If dilute H2SO4 is added in this tube then colourless vapours with smell of vinegar is formed. P gives deep red colour on reaction with neutral ferric chloride solution due to the formation of complex ion which decomposed on heating to form Q (brown-red precipitate). P and Q. respectively are
MEDIUM
A substance on treatment with dil. H2SO4 liberates a colourless gas which produces
(i) Turbidity with baryta water and (ii) turns acidified dichromate solution green.
The reaction indicates the presence of
HARD
A solution of a metal ion, when treated with KI, gives a red precipitate which dissolves in an excess of KI to give a colourless solution. Moreover, the solution of the metal ion on treatment with a solution of cobalt(II) thiocyanate gives rise to a deep blue crystalline precipitate. The metal ions is :
HARD
Solution of x + dil HCl  yellow ppt + gas having smell of burnt sulphur

Solution of x + KCN solution  Y +Z)

Y + excess of dil. HCl + FeCl3 solution

blood red colouration

Z + PbNO32 

white pptboiling white ppt M

solution of Y + PbNO32 solution boiling black ppt
HARD
A salt on treatment with dilute HCl gives a pungent smelling gas and a yellow precipitate. The salt gives green flame when tested. The solution gives a yellow precipitate with potassium chromate. The salt is
EASY
Which of the following anions would decolourise acidified KMnO4 solution
HARD
A pale yellow precipitate and a gas with pungent odour are formed on warming dilute hydrochloric acid with an aqueous solution containing :
MEDIUM
Which of the following salt will give white precipitate with the solution containing Pb2+ ions?
MEDIUM
A metal salt solution gives a yellow precipitate with silver nitrate. The precipitate dissolves in dilute nitric acid as well as in dilute ammonia solution. The solution contains:
MEDIUM
Experiment of detection of S-2 is given below in alkaline medium
S2-+Fe(CN)5NO2- product 
Select the correct statement about the experiment.
EASY
Water-soluble mixture   ii Filter i BaCl 2   white ppt.

Filtrate + (hot and conc.) HNO3 + BaCl2   white ppt. So, the mixture contains
MEDIUM

[X] + H2SO4 → [Y] a colourless gas with an irritating smell

Y+K2Cr2O7+H2SO4green solution

X and Y are, respectively -

EASY
A gas having a pungent odour and a pale yellow precipitate are formed on heating dilute hydrochloric acid with an aqueous solution containing :
HARD

Which of the following mixtures of ions can be separated by using an excess of an NaOH solution ?

MEDIUM
The equivalent masses of Na2CO3 when it is titrated with HCl using phenolphthalein and methyl orange separate experiments are