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On the basis of the following E° values, the strongest oxidizing agent is :

Fe(CN)64-Fe(CN)63-+e-;E°=-0.35V

Fe2+Fe3++e-  E°=-0.77V

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Important Questions on Electrochemistry

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Kohlrausch's law states that at :
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Al2O3 is reduced by electrolysis at low potentials and high currents. If 4.0×104 amperes of current is passed through molten Al2O3 for 6 hours, what mass of aluminum is produced (Assume 100% current efficiency, atomic mass of Al=27 g/mol) ?
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The equivalent conductance of M32. Solution of a weak monobasic acid is 8.0 mho cm2 eq-1 and at infinite dilution is 400 mho cm2 eq-1. The dissociation constant of this acid is:
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Given,

(i) Cu2++2e-Cu; E°=0.337 V

(ii) Cu+2+e-Cu+ ; E°=0.15 V

Electro potential, E° for the reaction

Cu++e-Cu will be:

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Which of the following expressions correctly represents the equivalent conductance at infinite dilution of Al2SO43. Given that Al3+ and SO42- are the equivalent conductances at infinite dilution of the respective ions?
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Consider the following relations for emf of an electrochemical cell:
(i) emf of cell = (Oxidation potential of anode) - (Reduction potential of cathode)
(ii) emf of cell = (Oxidation potential of anode) + (Reduction potential of cathode)
(iii) emf of cell = (Reduction potential of anode) + (Reduction potential of cathode)
(iv) emf of cell = (Oxidation potential of anode) - (Oxidation potential of cathode)

Which of the above relations are correct?

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An increase in equivalent conductance of a strong electrolyte with dilution is mainly due to :
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A solution contains Fe2+, Fe3+ and I- ions. This solution was treated with iodine at 35°C. E° for Fe3+|Fe2+ is +0.77V and E° for I2|I-=0.536V The favourable redox reaction is: